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SECTION 11

Appendices

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1. MSDS Request Forms, Sample Language for Requesting an MSDS on a Purchase Order,  Sample Letter Requesting an MSDS (Coming Soon)
2. CDC Manual Guides (Coming Soon)
3. CDC General Memoranda (Coming Soon)
4. Shelf Life of Unstable Chemicals
5. Proper Segregation of Chemical Classes
6. Form For Hazardous Chemical Inventory (Coming Soon)
7. Spill Control Guidelines (Coming Soon)
8. Guidelines For Proper Glove Selection
9. OSHA List of Select Carcinogens
10. List of Reproductive Toxins and Highly Acute Toxic Materials
11. Documentation of Training Form / Training Session Outline
12. OSHA List of Hazardous Chemicals
13. OSHA Standards
    • Hazard Communication (29 CFR 1910.1200)
    • Occupational Exposure to Hazardous Chemicals in Laboratories
      (29 CFR 1910.1450)

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Appendix A

1. CDC "Request For Material Safety Data Sheet" (Coming Soon)
2. Sample Language for Requesting an MSDS on a Purchase Order (Coming Soon)
3. Sample Letter Requesting an MSDS (Coming Soon)

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Appendix B

• CDC Manual Guides (Coming Soon)

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Appendix C

• CDC General Memoranda (Coming Soon)

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Appendix D

Shelf Life of Unstable Chemicals

Peroxide Hazard on Storage Discard After Three (3) Months
Isopropyl ether	Divinyl acetylene
Vinylidene chloride	Potassium metal
Sodium amide
Peroxide Hazard on Concentration Discard After One (1) Year
Ethyl ether	Tetrahydrofuran
Dioxane	Acetal
Methyl isobutyl ketone (glyme)	Ethylene glycol dimethyl ether
Vinyl ethers	Dicyclopentadiene
Diacetylene	Metal acetylene
Cumene	Tetrahydronaphthalene
Cyclohexane	t-Butyl alcohol
Hazardous to Peroxide Initiation of Polymerization Discard After One (1) Year
Styrene	Butadiene
Tetrafluoroethylene	Chlorotrifluoroethylene
Vinyl acetylene	Vinyl acetate
Vinyl chloride	Vinyl pyridine
Chlorobutadiene (Chloroprene)	9,10-Dihydroanthracene
Indene	Dibenzocyclopentadiene

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Appendix E

Proper Segregation of Chemical Classes

Partial List of Incompatible chemicals
(Toxic Hazards)

Substances in the left hand column should be stored and handled so that they cannot possibly accidentally contact corresponding substances in the center column, because toxic materials (right hand column) would be produced.

Arsenical Materials Any Reducing Agent Arsine
Azides	Acids	Hydrogen Azide
Cyanides	Acids	Hydrogen Cyanide
Hypochlorites	Acids	Chlorine or Hypochlorous Acid
Nitrates	Sulfuric Acid	Nitrogen Dioxide
Nitric acid	Copper, Brass, Heavy Metals	Nitrogen Dioxide
Nitrites	Acids	Nitrous Fumes
Phosphorus	Caustic Alkalies/ Reducers	Phosphine
Selenides	Reducers	Hydrogen Selenide
Sulfides	Acids	Hydrogen Sulfide
Tellurides	Reducers	Hydrogen Telluride

Reactive Chemicals

Reactive chemicals are substances which, under certain ambient or induced conditions, enter into violent reactions with spontaneous generation of large quantities of heat, light, gases (flammable and non-flammable), or toxicants that can be destructive to lives and property. Types of reactive chemicals have been loosely categorized:

Explosives

In general, protect explosive substances from shock, elevated temperatures, rapid temperature changes, and other reactive chemicals, Some examples: nitroglycerin, nitrocellulose, and organic peroxides. Many substances, when mixed, are potentially explosive (such as hydrazines and nitric acid).

Oxidizing and Reducing Substances

In many oxidizing and reducing reactions, both agents must be present. In some cases, one or the other substance may create a hazard by coming into contact with a normally innocuous substance. These reactions tend to generate heat and are often explosive, e.g., glycerol and potassium permanganate blended at room temperature for a few minutes react violently producing fire. The following examples of typical oxidizers may:

Increase Rate of Combustion
Aluminum nitrate	Perchloric acid 60% or less
Ammonium persulfate	Potassium chlorate
Barium chlorate	Potassium dichromate
Barium peroxide	Potassium nitrate
Calcium chlorate	Potassium persulfate
Calcium nitrate	Silver nitrate
Calcium peroxide	Silver nitrite
Cupric nitrate	Sodium perborate
Hydrogen peroxide	Sodium perchlorate
Lead nitrate	Sodium persulfate
Lithium hypochlorite	Strontium chlorate
Lithium peroxide	Strontium nitrate
Magnesium nitrate	Strontium nitrite
Magnesium perchlorate	Thorium nitrite
Magnesium peroxide	Uranium nitrate
Nickel nitrate	Zinc chlorate
Nitric acid 70% or less	Zinc peroxide
Cause Spontaneous Ignition
Calcium hypochlorite	Sodium chlorite (>40%)
Chromic acid	Sodium peroxide
Hydrogen peroxide (27.5-52%)	Sodium permanganate
Nitric acid	Trichloroisocyanuric acid
Potassium bromate	Sodium dichloroisocyanurate
Potassium permanganate
Decompose with Catalyst or Heat
Ammonium dichromate	Perchloric acid (60-72.5%)
Hydrogen peroxide (52-91%)	Potassium dichloroisocyanurate
Calcium hypochlorite (>50%)	Sodium dichloroisocyanurate
Cause Explosive Reaction when exposed to Catalyst, Heat, Shock, or Friction
Ammonium perchlorate	Perchloric acid
Ammonium permanganate	Potassium superoxide

Water Sensitive Substances

These chemicals react with water, steam, and moisture in the air to evolve heat and/or flammable or explosive gases. Isolate water-sensitive substances from other reactive compounds, and store in a cool, waterproof area. Some substances that liberate only hear are: strong acids and bases, acid anhydrides and sulfides. Some substances that liberate flammable gases when exposed to water are: alkali metals, hydrides, nitrites, carbides, and anhydrous metallic salts.

Air Reactive Substances

These materials are capable of rapid release of energy by themselves, as by self-reaction or polymerization, for example white phosphorous. Also included in this category are substances that can be easily ignited by common sources of heat when mixed with air, for example: alkali metals, ammonium nitrate, ammonium perchlorate, ammonium permanganate, benzoyl peroxide, boron hydrides, dinitrobenzene, lithium hydride, sulfur.

Acid Reactive Substances

These chemicals react with acid to evolve heat, flammable and/or explosive gases, and toxicants. Some examples are: alkali metals, hydroxides, carbides, nitrites, arsenic and related elements, cyanides, sulfides, and structural alloys (most metals).

Special Organic Compounds

These compounds are unstable and may decompose spontaneously or through contact with the immediate environment (air, water, and other reactants). Some examples: diazonium compounds, diazomethane, chlorination intermediates, butadiene, nitration intermediates, organic sulfates, polymerization reactions, and highly nitrated compounds.

Pyrophoric Agents

Pyrophoric agents burn when exposed to air. In general, they require absolute protection against air. Examples: phosphorus and activated zinc.

Incompatible Chemicals

The following is a partial listing of incompatible chemicals. A more complete listing may be found in NFPA and various laboratory and chemical reference manuals.

CHEMICAL	IS INCOMPATIBLE WITH
ACETIC ACID	Chromic acid, nitric acid, hydroxyl-containing compounds, ethylene glycol, perchloric acid, peroxides, and permanganates
ACETONE	Concentrated sulfuric and nitric acid mixtures or chloroform and bases
ACETYLENE	Copper tubing, halides, silver, mercury and their compounds
ALKALI METALS	Aluminum, calcium, lithium, magnesium, potassium and sodium with water or chlorinated hydrocarbon, carbon dioxide, halogens
AMMONIA, ANHYDROUS	Mercury, halogens, calcium hypochlorite, hydrogen fluoride
ANILINE	Nitric acid and hydrogen peroxide
AZIDES	Acids
BROMINE	Ammonia, acetylene, butadiene, butane, hydrogen, sodium carbide, turpentine
CHLORATES	Ammonium salts, acids, metal powders, sulfur, finely divided organic and combustible materials
CHROMIC ACID	Acetic acid, alcohol, camphor, flammable liquids, glycerol, naphthalene
CHLORINE	Ammonia, acetylene, butadiene, benzene and other petroleum fractions, hydrogen, sodium carbides, powdered metals
COPPER SALTS	Acetylene, hydrogen peroxide
CYANIDES	Acids
ETHYLENEDIAMINE	Greater than 3 percent with methylene chloride (explosive)
FLAMMABLE LIQUIDS	Ammonium nitrate, chromic acid, hydrogen peroxide, halogens, nitric acid, sodium peroxide
HYDROCARBONS	(Butane, Halogens, chromic acid, peroxides Propane, Benzene)
HYDROGEN PEROXIDE	Copper, chromium, iron, most metals and their salts, flammable fluids, aniline, and nitromethane
HYDROGEN SULFIDE	Nitric acid and oxidizing gases
IODINE	Acetylene, ammonia
CHEMICAL	IS INCOMPATIBLE WITH
MERCURY	Acetylene, hydrogen
METHYLENE CHLORIDE	Greater than 3 percent ethylenediamine (explosive)
NITRIC ACID	Ac	etic, chromic and hydrochloric acids, aniline, carbon, hydrogen sulfide, flammable fluids, or gases which are readily nitrated
OXYGEN	Oils, grease, hydrogen, flammable liquids, solids, and gases
OXALIC ACID	Mercury, silver
PERCHLORIC ACID	Acetic anhydride, alcohol, organic materials, e.g., wood, paper, grease, and oils
PHOSPHORUS	Air, alkalis, oxygen, reducing agents
PHOSPHORUS PENTOXIDE	Water
SODIUM	Carbon dioxide, carbon tetrachloride, water
SODIUM PEROXIDE	Any oxidizable substances; acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerol, ethylene glycol, ethyl acetate, methanol
SULFURIC ACID	Potassium chlorate, potassium perchlorate, potassium permanganate

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Appendix F

Hazardous Chemical Inventory Form (Coming Soon)

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Appendix G

Spill Control Guidelines (Coming Soon)

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Appendix H

Guidelines for Proper Glove Selection

(see Personal Protective Equipment Program Manual Appendix)

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Appendix I

OSHA Select Carcinogens

SUBSTANCE	CAS #	IARC 1	IARC 2A	IARC 2B	NTP 1	NTP 2	OSHA
ACETALDEHYDE	75-07-0			X
ACETAMIDE	60-35-5			X
2-ACETYLAMINOFLUORENE	53-96-3					X	X
ACRYLAMIDE	79-06-1			X
ACRYLONITRILE	107-13-1		X			X	X
ADRIAMYCIN	23214-92-8		X			X	X
AFLATOXINS	NONE	X				X
2-AMINOANTHRAQUINONE (AAQ)	177-79-3					X
O-AMINOAZOTOLUENE	97-56-3			X		X
4-AMINODIPHENYL	92-67-1	X			X		X
1-AMINO-2-METHYL- ANTHRAQUINONE	82-28-0					X
2-AMINO-5 (5-NITRO-2-FURYL) 1,3,4-THIADIAZOLE	59716-87-9			X
3-AMINO-1,2, 3-TRIAZOLE	61-82-5			X		X
AMITROLE	61-82-5			X		X
AMOSITE	12172-73-5	X			X		X
ANISIDINE (O,P-ISOMERS)	29191-52-4		X			X
O-ANISIDINE HYDROCHLORIDE	134-29-2					X
ARSENIC & SOLUBLE COMPOUNDS, AS	7440-38-2	X			X		X
ASBESTOS, AMOSITE	12172-73-5	X			X		X
ASBESTOS, CHRYSOTILE	12001-29-5	X			X		X
ASBESTOS, CROCODOLITE	12001-28-4	X			X		X
ASBESTOS, OTHER FORMS	NONE	X			X		X
AURAMINE MANUFACTURE	492-80-8			X
AZASERINE	115-02-6			X
AZATHIOPRINE	446-86-6	X			X
BENZAL CHLORIDE	98-87-3			X
BENZ(A)ANTHRACENE	56-55-3		X			X
BENZENE	71-43-2	X			X		X
BENZIDINE	92-87-5	X			X		X
BENZOTRICHLORIDE	106-51-4			X		X
BENZO(A)PYRENE	50-32-8		X			X
BENZO(B) FLUOROANTHENE	205-99-2			X		X
BENZYL CHLORIDE	100-44-7			X
BENZYL VIOLET 4B	1694-09-3			X
BERYLLIUM AND COMPOUNDS, AS BE	7440-41-7		X	"		X
BISCHLOROETHYL NITROSOUREA	154-93-8		X			X
BITUMEN	8052-42-4			X
1,3-BUTADIENE	106-99-0			X		X
1,4-BUTANEDIOL DIMETHYLSULFONATE	55-98-1	X			X
BUTYLPHENO- XYISOPROPYL CHLOROETHYL SULFITE	140-57-8			X
B-BUTYROLACTONE	3068-88-0			X
CADMIUM CHLORIDE	10108-64-2		X
CADMIUM DUSTS AND SALTS, AS CD	7440-43-9		X			X
CALCIUM CHROMATE	13756-19-0					X
CARBON TETRACHLORIDE	56-23-5			X		X
CHLORAMBUCIL	305-03-3	X			X		X
CHLORDECONE	143-05-0			X		X
CHLORENDIC ACID	115-28-6					X
CHLORINATED CAMPHENE	8001-35-2					X
CHLORINATED PARAFFINS	108171-26-2					X
1-CHLORO-2,3-EPOXYPROPANE	106-89-8		X			X
1-(2-CHLOROETHYL)- 3-CYCLOHEXYL- 1-NITROSOUREA	13010-47-4		X			X
CHLOROETHYLENE	75-01-4	X			X		X
CHLOROFORM	67-66-3			X		X
BIS(CHLORO- METHYL)ETHER	542-88-1	X			X		X
CHLOROMETHYL METHYL ETHER	107-30-2	X			X		X
3-CHLORO-2-METHYL PROPENE	563-47-3					X
4-CHLORO-O- PHENYLDIAMINE	95-83-0			X		X
4-CHLORO-TOLUIDINE	95-69-2			X
2-CHLOROPHENOL	95-57-8			X
3-CHLOROPHENOL	108-43-0			X
4-CHLOROPHENOL	106-48-9			X
CHROMIUM (VI) COMPOUNDS, AS CR, WATER SOLUBLE	NONE	X			X		X
CHROMIUM (VI) COMPOUNDS, AS CR, CERTAIN WATER INSOLUBLE	NONE	X			X		X
CHROMIUM TRIOXIDE	1333-82-0					X
CHRYSOTILE	12001-29-5	X			X		X
CISPLATIN	15663-27-1		X
CITRUS RED NO. 2	6358-53-8			X
COAL TAR PITCH VOLATILES	65996-93-2	X			X
COKE OVEN EMISSIONS	NONE	X			X		X
P-CRESIDINE	120-71-8			X		X
CRISTOBALITE	14464-46-1		X
CROCIDOLITE	12001-28-4	X			X		X
CUPFERRON	135-20-6					X
CYCASIN	14901-08-7			X
CYCLOPHOSPHAMIDE	50-18-0	X			X		X
DDT (DICHLORODIPHENYL -TRICHLORETHANE)	50-29-3			X		X
DACARBAZINE	4342-03-4			X		X
DAUNOMYCIN	20830-31-3			X
N,N'-DIACETYLBENZIDINE	613-35-4			X
2,4-DIANIMOANISOLE	615-05-4			X
2,4-DIAMINOANISOLE SULFATE	39156-41-7			X		X
4,4'-DIAMINODIPHENYL ETHER	101-80-4			X		X
2,4-DIAMINOTOLUENE	95-80-7			X		X
DIBENZ(A,H)ACRIDINE	226-36-8			X		X
DIBENZ(A,J)ACRIDINE	224-42-0			X		X
DIBENZA(A, H)ANTHRACENE	53-70-3		X			X
7H-DIBENZO(C, G)CARBAZOLE	194-59-2		X			X
DIBENZO(A,E)PYRENE	192-65-4			X		X
DIBENZO(A, H)PYRENE	189-64-0			X		X
DIBENZO(A,I)PYRENE	189-55-9			X		X
1,2-DIBROMO-3- CHLOROPROPANE	96-12-8			X		X
1,2-DIBROMOETHANE	106-93-4		X			X
3,3'-DICHLOROBENZIDINE	91-94-1			X		X	X
3,3'-DICHLORO-4,4'- DIAMINODIPHENYL ETHER	28434-86-8			X		X
1,2-DICHLOROETHANE	107-06-2			X		X
DICHLOROMETHANE	75-09-2			X		X
2,4-DICHLOROPHENYL-P- NITROPHENYL ETHER	1836-75-5			X		X
1,3-DICHLOROPROPENE	542-75-6			X		X
DIEPOXYBUTANE	1464-53-5			X		X
DIETHYLDITHIOCARBAMIC ACID 2-CHLORALLYL ESTER	95-06-7			X		X
DI(2-ETHYLHEXYL)PHTHALATE	117-81-7			X		X
1,2-DIETHYLHYDRAZINE	1615-80-1			X
DIETHYLSTILBESTROL	56-53-1	X			X		X
DIETHYL SULFATE	64-67-5		X			X
DIGLYCIDYL RESORCINOL ETHER	101-90-6			X	X
DIHYDROSAFROLE	94-58-6			X
3,3'-DIMETHOXYBENZIDINE	119-90-4					X
4-DIMETHYLAMINOAZO -BENZENE	60-11-7			X		X	X
3,3'-DIMETHYLBENZIDENE	119-93-7			X		X
DIMETHYL CARBOMYL CHLORIDE	79-44-7		X			X
1,1-DIMETHYLHYDRAZINE	57-14-7			X		X
1,2-DIMETHYLHYDRAZINE	540-73-8			X
N,N-DIMETHYL -NITROSOAMINE	65-72-9		X			X	X
DIMETHYL SULFATE	77-78-1		X			X
1,4-DIOXANE	123-91-1			X		X
DIRECT BLACK 38 (TECHNICAL GRADE)	1937-37-7					X
DIRECT BLUE 6 (TECHNICAL GRADE)	2602-46-2					X
DI-SEC-OCTYL- PHTHALATE	117-81-7			X	X	X	X
EPICHLOROHYDRIN	106-89-8		X			X
1,2-EPOXYPROPANE	75-56-9		X
ESTROGENS, CONJUGATED (INDIRECT)	NONE				X
ETHYL ACRYLATE	140-88-5			X		X
ETHYLENE DIBROMIDE	106-34-4		X			X
ETHYLENE DICHLORIDE	107-06-2			X		X
ETHYLENE OXIDE	75-21-8		X			X
ETHYLENE THIOUREA	96-45-7			X		X
ETHYLENIMINE	151-56-4						X
ETHYL METHANE SULPHONATE	62-50-0		X
FORMALDEHYDE	50-00-0		X			X	X
2-(2-FORMYLHYDRAZINO)-4- (5-NITRO-2- FURYL)THIAZOLE	3570-75-0			X
GLYCIDALDEHYDE	765-34-4			X
HEMATITE UNDERGROUND MINING	NONE	X
HEXACHLOROBENZENE	118-74-1			X		X
HEXAMETHYL PHOSPHORAMIDE	680-31-9			X		X		HYDRAZINE	302-01-2			X		X
HYDRAZINE SULFATE	10034-93-2					X
HYDRAZOBENZENE	122-66-7					X
INDENO(1,2,3-CD)PYRENE	193-30-5			X		X
IRON DEXTRAN COMPLEX	9004-66-4			X		X
ISOPROPYL OIL	NONE				X
KEPONE	143-50-0			X		X
LASIOSCARPINE	303-34-4			X
LEAD, INORGANIC DUSTS AND FUMES, AS PB	7439-92-1			X
LEAD ACETATE	301-04-2					X
LINDANE	58-89-9					X
MAGENTA MANUFACTURE	632-99-5	X
MELPHALAN	148-82-3	X			X
MERPHALAN	531-76-0			X
METHYLAZOXYMETHANOL	590-96-5			X
METHYLAZOXYMETHANOL SULFATE	592-62-1			X
5-METHYLCHRYSENE	NONE					X
METHYLENE CHLORIDE	75-09-2			X
4,4'-METHYLENE BIS(2-CHLOROANILINE)	101-14-4		X			X
4,4'-METHYLENE DIANILINE	101-77-9			X		X
4,4'-METHYLENE BIS(2-METHYLANILINE)	838-88-0			X
4,4'-METHYLENE BIS(N,N-DIMETHYL BENZENAMINE)	101-61-1					X
METHYL METHANESULPHONATE	66-27-3			X
2-METHYL-1- NITROANTHRAQUINONE	129-15-7			X
N-METHYL-N'-NITRO- N-NITROSOQUANIDINE	70-25-7		X
METHYLTHIOURACIL	56-04-2			X
METRONIDAZOLE	443-48-1			X		X
MICHLER'S KETONE	90-94-8					X
MIREX	2385-85-5			X		X
MITOMYCIN C	50-07-7			X
MONOCROTALINE	315-22-0			X
MUSTARD GAS	505-60-2	X			X		X
NAFENOPIN	3771-19-5			X
NAPHTHA (COAL TAR)	8030-30-6	X
ALPHA-NAPHTHYLAMINE	134-32-7						X
BETA-NAPHTHYLAMINE	91-59-8	X			X		X
NICKEL, METAL	7440-02-0	X				X
NICKEL, INSOLUBLE COMPOUNDS, AS NI	7440-02-0	X				X
NICKEL, SOLUBLE COMPOUNDS, AS NI	7440-02-0	X				X
NICKEL CARBONYL, AS NI	7440-02-0					X
NICKEL SULFIDE ROASTING, FUME	NONE				X
NIRIDAZOLE	61-57-4			X
NITRILOTRIACETIC ACID (NTA)	139-13-9					X
5-NITROACENAPHTHENE	602-87-9			X
4-NITROBIPHENYL	92-93-3						X
1-[(NITROFURFURYLIDENE)AMINO]- 2-IMIDAZOLIDINONE	555-84-0			X
N-[4-(5-NITRO-2-FURYL) -2-THIAZOLYL] ACETAMIDE	531-82-8			X
NITROGEN MUSTARD	51-75-2		X			X
NITROGEN MUSTARD N-OXIDE	302-70-5			X
5-NITRO-O-ANISIDINE	99-59-2					X
2-NITROPROPANE	79-46-9			X
N-NITROSODI-N -BUTYLAMINE (DBN)	924-16-3			X		X
N-NITROSODIETHANOLAMINE (NDELA)	1116-54-7			X		X
N-NITROSODIETHYLAMINE (NDEA)	55-18-5		X			X
N-NITROSODIMETHYLAMINE	62-75-9		X			X	X
P-NITROSODIPHENYLAMINE	156-10-5					X
N-NITROSODI-N- PROPYLAMINE (NDP)	621-64-7			X		X
N-NITROSO-N- ETHYLUREA (ENU)	759-73-9					X
N-NITROSOMETHYLETHYLAMINE	10595-95-6			X
N-NITROSO-N- METHYLUREA (NMU)	684-93-5			X		X
N-NITROSOMETHYLVINYLAMINE (NMVA)	13256-13-8			X		X
N-NITROSOMORPHOLINE (NMOR)	59-89-2			X		X
N'-NITROSONORNICOTINE (NNN)	16543-55-8			X		X
N-NITROSOPIPERIDINE (NPIP)	100-75-4			X		X
N-NITROSOPYRROLIDINE (NPYR)	930-55-2			X		X
N-NITROSOSARCOSINE (NSAR)	13256-22-9			X		X
OIL ORANGE SS	2646-17-5			X
4,4'-OXYDIANILINE	101-80-4			X
OXYMETHOLONE	434-07-1					X
PANFURAN S	794-93-4			X
PARTICULATE POLYCYCLIC AROMATIC HYDROCARBONS	65995-93-2	X				X
PERCHLOROETHYLENE	127-18-4					X
PHENACETIN	66-44-2		X			X
PHENAZOPYRIDE	94-78-0					X
PHENAZOPYRIDE HYDROCHLORIDE	136-40-3			X		X
PHENOXYACETIC ACID HERBICIDES	NONE			X
PHENOXYBENZAMINE HYDROCHLORIDE	63-92-3			X		X
PHENYTOIN (+ SODIUM SALTS)	57-41-0			X		X
POLYBROMINATED BIPHENYLS (PBBs)	36355-01-8			X		X
POLYCHLORINATED BIPHENYLS (PCBs)	1336-36-3		X			X
PONCEAU MS	3761-53-3		X
PONCEAU 3R	65997-15-1		X
PROCARBAZINE	671-16-9					X
PROCARBIZINE HYDROCHLORIDE	366-70-1		X			X
PROGESTERONE (INDIRECT)	NONE					X
PROPANE SULTONE	1120-71-4			X		X
BETA-PROPIOLACTONE	57-57-8			X		X	X
PROPYLENE IMINE	75-55-8					X
PROPYLENE OXIDE	75-56-9		X			X
PROPYLTHIOURACIL	51-52-5			X		X	X
QUARTZ	14808-60-7		X
RESERPINE	50-55-5					X
SACCHARIN	81-07-2			X		X
SAFROLE	94-59-7			X		X
SELENIUM SULFIDE	7446-34-6					X
SILICA-CRYSTALLINE, CRISTOBALITE	14464-46-1		X
SILICA-CRYSTALLINE, QUARTZ	14808-60-7		X
SILICA-CRYSTALLINE, TRIDYMITE	15468-32-3		X
SILICA-CRYSTALLINE, TRIPOLI	1317-95-9		X
STERIGMATOCYSTIN	10048-13-2			X
STR valign=bottom EPTOZOTOCIN	18883-66-4			X		X
STR valign=bottom ONTIUM CHROMATE, AS CR	7789-06-2					X
STYRENE, MONOMER	100-42-5			X
TALC (CONTAINING ASBESTOS FIBERS)	NONE	X			X		X
2,3,7,8-TETRACHLORODIBENZO -P-DIOXIN	1746-01-6			X		X
TETRACHLOROETHYLENE	127-18-4			X		X
TETRACHLOROMETHANE	56-23-5			X		X
THIOACETAMIDE (TTA)	62-55-5			X		X
4,4'-THIODIANALINE	139-65-1			X
THIOUREA	62-56-6			X		X
THORIUM DIOXIDE	NONE				X
O-TOLIDINE	119-93-7			X		X
TOLUENE-2, 4-DIAMINE	95-80-7			X		X
TOLUENE-2, 4-DIISOCYANATE (TDI)	584-84-9			X		X
O-TOLUIDINE	95-53-4			X		X
O-TOLUIDINE HYDROCHLORIDE	636-21-5					X
TOXAPHENE	8001-35-2			X		X
TREMOLITE	1332-21-4	X			X		X
TREOSULPHAN	299-75-2	X
TRICHLOROMETHANE	67-66-3			X		X
2,4,6-TRICHLOROPHENOL	88-06-6					X
TRIDYMITE	15468-32-3		X
TRIPOLI	1317-95-9		X
TR valign=bottom IS(1-AZIRIDINYL) PHOSPHINE SULFIDE	52-24-4		X			X
TR valign=bottom IS(2,3-DIBROMOPROPYL) PHOSPHATE	126-72-7		X			X
TRYPAN BLUE (COMMERCIAL GRADE)	72-57-1			X
URACIL MUSTARD	66-75-1			X
URETHANE (ETHYL CARBAMATE)	51-79-6			X		X
VINYL BENZENE	100-42-5			X
VINYL BROMIDE	593-60-2		X
VINYL CHLORIDE	75-01-4	X			X		X
VINYL CYANIDE	107-13-1		X			X	X
ZINC BERYLLIUM SILICATE	39413-47-3		X			X
ZINC CHROMATES, AS CR	NONE				X

---

Appendix J

Reproductive Toxins and Highly Acute Toxic Materials

Reproductive Toxins

Acrylonitr ile
Aniline
Arsenic and its compounds
Benzene
Benzo(a)pyrene
Beryllium
Boric acid (Boron)
Cadmium and its compounds
Carbon monoxide
Chlordecone (Kepone)
Chloroform
Chloroprene
Dibromochloropropane (DBCP)
Dichlorobenzene
1,1-Dichloroethane
Dichloromethane
Dioxane
Epichlorohydrin
Ethylene Dibromide
Ethylene Dichloride
Ethylene Oxide
Fluorocarbons
Formaldehyde
Formamides
Lead (Organic)
Manganese and its compounds
Mercury and its compounds (Inorganic)
Methyl n-butyl ketone
Methyl chloroform
Methyl ethyl ketone (MEK)
Nitrogen Dioxide
Ozone
Platinum and its compounds
Polybrominated biphenyls (PBB)
Polychlorinated bipenyls (PCB)
Selenium and its compounds
Styrene
Tellurium and its compounds
Tetr achloroethylene
Thallium and its compounds
Toluene
Toluene-2,4-diisocyanate
o-Toluidine
Trichloroethylene
Vinyl chloride
Vinylidene chloride
Xylene

Highly Acute Toxic Materials

Abrin
N-Acetoxy-2-acetylaminofluorene
Actinomycin D
Aldicarb
o-Aminoazobenzene
2-Aminofluorene
Anabasine
Apholate
Arsenious Acid, Monosodium Salt
Arsenic tr ioxide
Atr opine
N,N-bis(2-chloromethyl)-2-Naphthylamine
Bromoethyl methanesulfonate
1,4-Butanediol dimethylsulfonate
Canthardin
2-chloro-4-Dimethyl-amino-6-methylpyrlmidine
Cyanogen Bromide
Diazomethane
Digalen
Digifolin
Digoxin
7,12-Dimethylbeze[a]anthracene
3,3'-Dimethoxybenzidine
3,3'-Dimethylbenzidine
Dimetthylethylenimine
1,2-Dimethylhydrazine
3,3'-Dimethoxybenzidine, dihydrochloride
1,4-Dinitr osopoperazine
Duboisine
Ethionine
Ethylenimine
Ethylene glycol dinritr ate
Ethyl methanesulfonate
Fluroactetic acid
Gitalin
Heroin
Hexaaethyl tetr aphosphate
Hydrazoic acid
Hydrocyanic acid
N-Hydroxy-2-acetylaminofluorene
Hyoscyamine
Inorganic arsenic
Isobenzan
K-Str ophanthin
Lanatoside
Lysergic acid diethylamide
3-Methylcholanthrene
Methyl chloromethyl ether
4,4'-Methylene bis-(2-chloraniline)
Methylhydrazine
Methyl methanesulfonate
Nicotine salicylate
N-[4-(5-Nitr o-2-furyl)-2-thiazoly]-formamide
Nitr oglycerin
N-Nitr oquinoline-1-oxide
N-Nitr osodimethylamine
N-Nitr oso-N-methylurethane 2H-1,3,2-oxazaphosphorine ,2[bis(2-chloroethyl) Amino]tetr ahydro-,2 oxide
Pantopon
Parathion
Paroxon
Phosphine
Phosphorodithioic acid
Phosphorous (Yellow)
Propylenimine
2-propyl-piperidine
Ricin
Scopolamine
Sarin
Sodium Azide
Sodium Selenate
Sulfotepp
Tabun
Tepp
2,3,7,8-Tetr achlorodibenzofuran
Thimet
m-Toluenediamine
Uracil mustard

---

Appendix K

TRAINING SESSION OUTLINE AND FORMAT

TRAINER:

 

BUILDING AND LOCATION:

C/I/O:

TRAINING TOPIC(S):

 

ATTACH COPIES OF ALL HANDOUTS PROVIDED TO TRAINEES.

TRAINING OUTLINE

FORMAT USED (VIDEOTAPE, FILM, SLIDES, SPEAKER, ETC.)

 

---

 

Appendix L

OSHA List of Hazardous Chemicals

ACETALDEHYDE
ACETAMIDE
ACETIC ACID
ACETIC ANHYDRIDE
ACETONE
ACETONItr ILE
ACETYLAMINOFLUORENE, 2-
ACETYLENE
ACETYLENE DICHLORIDE
ACETYLENE TETRABROMIDE
ACETYLSALICYLIC ACID (ASPIRIN)
ACROLEIN
ACRYLAMIDE
ACRYLIC ACID
ACRYLONITRILE
ACTINOMYCIN D
ADRIAMYCIN
AFLATOXINS
ALDRIN
ALLYL ALCOHOL
ALLYL CHLORIDE
ALLYL GLYCIDYL ETHER (AGE)
ALLYL PROPYL DISULFIDE
ALUMINA
ALUMINUM, METAL DUST, AS AL
ALUMINUM, PYRO POWDERS, AS AL
ALUMINUM, SOLUBLE SALTS, AS AL
ALUMINUM, WELDING FUMES, AS AL
ALUMINUM, ALKYLS, NOT OTHERWISE
CLASSIFIED, AS AL
ALUMINUM OXIDE, AS AL
AMINOANTHRAQUINONE (AAQ), AMINOAZOTOLUENE, O-
AMINOBIPHENYL, 4-
AMINOETHANOL, 2-
AMINO-2-METHYLANTHRAQUINONE, 1-
AMINO-5-(5-NITRO-2-FURYL)- -1,
3,4-THIADIADIAZOLE, 2-
AMINOPYRIDINE, 2-
AMINO-1,2,4-TRIAZOLE, 3-
AMITROLE
AMMONIA
AMMONIUM CHLORIDE FUME
AMMONIUM PERFLUOROOCTANOATE
AMMONIUM SULFAMATE
AMOSITE
AMYL ACETATE, N-
AMYL ACETATE, SEC-
ANILINE & HOMOLOGUES
ANISIDINE (O-,P-ISOMERS)
ANISIDINE HYDROCHLORIDE, O-
ANTIMONY & COMPOUNDS, AS SB
ANTIMONY TRIOXIDE, HANDLING AND USE, AS SB
ANTIMONY TRIOXIDE, PRODUCTION
ANTU
ARAMITE
ARGON
ARSENIC & SOLUBLE COMPOUNDS, AS AS
ARSENIC TRIOXIDE PRODUCTION
ARSINE
ASBESTOS, AMOSITE
ASBESTOS, CHRYSOTILE
ASBESTOS, CROCIDOLITE
ASBESTOS, OTHER FORMS
ASPHALT (PETROLEUM) FUMES
ATRAZINE
AURAMINE MANUFACTURE
AZASERINE
AZATHIOPRINE
AZINPHOS-METHYL
AZO DYES
BARIUM, SOLUBLE COMPOUNDS, AS BA
BARIUM SULFATE
BAYTEX (FENTOIN)
BEECH WOOD DUST
BENOMYL
BENZAL CHLORIDE
BENZ(A)ANTHRACENE
BENZENE
BENZIDINE
BENZOQUINONE, P-
BENZOTRICHLORIDE
BENZOYL PEROXIDE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZYL CHLORIDE
BENZYL VIOLET 4B
BERYLLLIUM AND COMPUNDS, AS BE
BIPHENYL
BISCHLOROETHYL NITROSOUREA (BCNU)
BISMUTH TELLURIDE (UNDOPED)
BISMUTH TELLURIDE (SE-Doped)
BITUMEN
BORATES, TETRA, SODIUM SALTS, ANHYDROUS
BORATES, TETRA, SODIUM SALTS, DECAHYDRATE
BORATES, TETRA, SODIUM SALTS, PENTAHYDRATE
BORON OXIDE
BORON TRIBROMIDE
BORON TRIFLUORIDE
BROMACIL
BROMINE
BROMINE PENTAFLUORIDE
BROMOCHLOROMETHANE
BROMOFORM
BUTADIENE, 1,3-
BUTANE
BUTANEDIOL DIMETHYSULFONATE, 1,4-
BUTANETHIOL
BUTANONE, 2-
BUTOXYETHANOL, 2-
BUTYL ACETATE, N-
BUTYL ACETATE, SEC-
BUTYL ACETATE, TERT-
BUTYL ACRYLATE, N-
BUTYL ALCOHOL, N-
BUTYL ALCOHOL, SEC-
BUTYL ALCOHOL, TERT-
BUTYLAMINE, N-
BUTYL CHROMATE, AS CR03, TERT-
BUTYL GLYCIDYL ETHER (BGE), N-
BUTYL LACTATE, N-
BUTYL MERCAPTAN
BUTYLPHENOL, O-SEC-
BUTYLPHENOXYISOPROPYL CHLORO-
ETHYL SULFITE (ARAMITE)
BUTYLTOLUENE, P-TERT-
BUTYROLACTONE, BETA-
CADMIUM CHLORIDE
CADMIUM DUSTS & SALTS, AS CD
CADMIUM OXIDE FUME, AS CD
CADMIUM OXIDE PRODUCTION
CALCIUM CARBONATE
CALCIUM CHROMATE, AS CR
CALCIUM CYANAMIDE
CALCIUM CYCLAMATE
CALCIUM HYDROXIDE
CALCIUM OXIDE
CALCIUM SILICATE
CALCIUM SULFATE
CAMPHOR, SYNTHETIC
CAPROLACTAM DUST
CAPROLACTAM VAPOR
CAPTAFOL
CAPTAN
CARBARYL
CARBOFURAN
CARBON BLACK
CARBON DIOXIDE
CARBON DISULFIDE
CARBON MONOXIDE
CARBON TETRABROMIDE
CARBON TETRACHLORIDE
CARBONYL CHLORIDE
CARBONYL FLUORIDE
CATECHOL
CELLULOSE (PAPER FIBER)
CESIUM HYDROXIDE
CHLORAMBUCIL
CHLORAMPHENICOL
CHLORDANE
CHLORDECONE (KEPONE)
CHLORENDIC ACID
CHLORINATED CAMPHENE
CHLORINATED DIPHENYL OXIDE
CHLORINATED PARAFFINS
CHLORINE
CHLORINE DIOXIDE
CHLORINE TRIFLUORIDE
CHLORNAPHAZINE
CHLOROACETALDEHYDE
CHLOROACETONE
CHLOROACETOPHENONE, ALPHA-
CHLOROACETYL CHLORIDE
CHLOROBENZENE
CHLOROBENZILATE
CHLOROBENZYLIDENE MALONO-NITRILE, O-
CHLOROBROMOMETHANE
CHLORO-1,3-BUTADIENE, 2-
CHLORODIFLUOROMETHANE
CHLORO,2,3-EPOXY-PROPANE, 1-
CHLORODIPHENYL (42% CHLORINE)
CHLORODIPHENYL (54% CHLORINE)
CHLOROETHANE
CHLOROETHANOL, 2-
CHLOROETHYL)-3-CYCLOHEXYL-1-
NITROSOUREA, 1-(2-
CHLOROETHYLENE
CHLOROFLUOROMETHANE
CHLOROFORM
(CHLOROMETHYL) ETHER, BIS-
CHLOROMETHYL METHYL ETHER
CHLORO-2-METHYLPROPENE, 3-
CHLORO-1-NITROPROPANE, 1-
CHLORO-O-PHENYLENEDIAMINE, 4-
CHLORO-O-TOLUIDINE, 4-
CHLOROPENTAFLUOROETHANE
CHLOROPHENOL, 2-
CHLOROPHENOL, 3-
CHLOROPHENOL, 4-
CHLOROPICRIN
CHLOROPRENE, BETA-
CHLOROPROPIONIC ACID
CHLOROSTYRENE, O-
CHLOROTOLUENE, O-
CHLORO-6-(TRICHLOROMETHYL) PYRIDINE, 2-
CHLORPYRIFOS
CHROMATES, ALKALINE, AS CR
CHROMIC ACID AND CHROMATES, AS CRO3
CHROMITE ORE PROCESSING (CHROMATE), AS CR
CHROMIUM (II) COMPOUNDS, AS CR
CHROMIUM (III) COMPOUNDS, AS CR
CHROMIUM (VI) COMPOUNDS, AS CR, WATER SOLUBLE
CHROMIUM (VI) COMPOUNDS, AS CR, CERTAIN WATER INSOLUBLE
CHROMIUM METAL
CHROMIUM TRIOXIDE
CHROMYL CHLORIDE
CHRYSENE
CHRYSOTILE
CISPLATIN
CITRUS RED NO. 2
CLOPIDOL
COAL DUST
COAL TAR PITCH VOLATILES, AS BENZENE SOLUBLES
COBALT, METAL DUST & FUME, AS CO
COBALT CARBONYL, AS CO
COBALT HYDROCARBONYL, AS CO
COKE OVEN EMISSIONS
COPPER FUME
COPPER DUSTS & MISTS, AS CU
COTTON DUST, RAW
CRESIDINE, P-
CRESOL, ALL ISOMERS
CRISTOBALITE
CROCIDOLITE
CROTONALDEHYDE
CRUFOMATE
CUMENE
CUPFERRON
CYANAMIDE
CYANIDE, CALCIUM, AS CN
CYANIDE, POTASSIUM, AS CN
CYANIDE, SODIUM, AS CN
CYANOGEN
CYANOGEN CHLORIDE
CYCASIN
CYCLAMATES
CYCLOHEXANE
CYCLOHEXANOL
CYCLOHEXANONE
CYCLOHEXENE
CYCLOHEXYLAMINE
CYCLONITE
CYCLOPENTADIENE
CYCLOPENTANE
CYCLOPHOSPHAMIDE
CYHEXATIN
D, 2,4-
DDT (DICHLORODIPHENYLTRI-CHLOROETHANE)
DACARBAZINE
DAUNOMYCIN
DECABORANE
DEMETON-METHYL
DEMETON (SYSTOX)
DIACETONE ALCOHOL
DIACETYLBENZIDINE, N,N'-
DIAMINOANISOLE, 2,4-
DIAMINOANISOLE SULFATE, 2,4-
DIAMINODIPHENYL ETHER, 4,4'-
DIAMINODIPHENYLMETHANE, 4,4'-
DIAMINOETHANE, 1,2-
DIAMINOTOLUENE, 2,4-
DIATOMACEOUS EARTH
DIAZINON
DIAZOMETHANE
DIBENZ(A,H)ACRIDINE
DIBENZ(A,J)ACRIDINE
DIBENZ(A,H)ANTHRACENE
DIBENZO(C,G)CARBAZOLE, 7H-
DIBENZO(A,E)PYRENE
DIBENZO(A,H)PYRENE
DIBENZO(A,I)PYRENE
DIBORANE
DIBROM
DIBROMO-3-CHLOROPROPANE (DBCP), 1,2-
DIBROMOETHANE, 1,2-
DIBUTYLAMINOETHANOL, 2-N-
DIBUTYL PHENYL PHOSPHATE
DIBUTYL PHTHALATE
DICHLOROACETYLENE
DICHLOROBENZENE, O-
DICHLOROBENZENE, P-
DICHLOROBENZIDINE, 3,3'-
DICHLORO-4,4'-DIAMINODIPHENYL ETHER, 3,3'-
DICHLORODIFLUOROMETHANE
DICHLORO-5,5-DIMETHYL HYDAN-TOIN, 1,3-
DICHLORODIPHENYL-TRICHLORO-ETHANE
DICHLOROETHANE, 1,1-
DICHLOROETHANE, 1,2-
DICHLOROETHYLENE, 1,1-
DICHLOROETHYLENE, 1,2-
DICHLOROETHYL ETHER
DICHLOROFLUOROMETHANE
DICHLOROMETHANE
DICHLORO-1-NITROETHANE, 1,1-
DICHLOROPHENOXY ACETIC ACID, 2,4-
DICHLOROPHENYL-P-NITROPHENYL ETHER, 2,4- (TOK)
DICHLOROPROPANE, 1,2-
DICHLOROPROPENE,1,3-
DICHLOROPROPIONIC ACID, 2,2-
DICHLOROTETRAFLUOROETHANE
DICHLORVOS
DICROTOPHOS
DICYCLOPENTADIENE
DICYCLOPENTADIENYL IRON
DIELDRIN
DIEPOXYBUTANE
DIETHANOLAMINE
DIETHYLAMINE
DIETHYLAMINOETHANOL, 2-
DIETHYLCARBAMOYL CHLORIDE
DIETHYLDITHIOCARBAMIC ACID 2-CHLORALLYL-ESTER
DIETHYLENE TRIAMINE
DIETHYL ETHER
DI(2-ETHYLHEXYL)PHTHALATE
DIETHYLHYDRAZINE, 1,2-
DIETHYL KETONE
DIETHYL PHTHALATE
DIETHYLSTILBESTROL
DIETHYL SULFATE
DIFLUORODIBROMOMETHANE
DIGLYCIDYL ETHER (DGE)
DIGLYCIDYL RESORCINOL ETHER
DIHYDROSAFROLE
DIHYDROXYBENZENE
DIISOBUTYL KETONE
DIISOPROPYLAMINE
DIMETHOXYBENZIDINE, 3,3'-
DIMETHOXYMETHANE
DIMETHYL ACETAMIDE, N,N-
DIMETHYLAMINE
DIMETHYLAMINOAZOBENZENE, 4-
DIMETHYLAMINOBENZENE
(DIMETHYLAMINO)METHYLIMINO]-5-[2-5-NITRO-2-FURYL)VINYL]-1,3, 4-OXADIAZOL, TRANS-2
DIMETHYLANILINE
DIMETHYLBENZENE
DIMETHYLBENZIDINE, 3,3-
DIMETHYL CARBAMOYL CHLORIDE
DIMETHYL-1,2-DIBROMO-2-DI-CHLOROETHYL
PHOSPHATE
DIMETHYL ETHER
DIMETHYL ETHYL AMINE, N,N-
DIMETHYLFORMAMIDE
DIMETHYL-4-HEPTANONE, 2,6-
DIMETHYLHYDRAZINE, 1,1-
DIMETHYLHYDRAZINE, 1,2-
DIMETHYLNITROSOAMINE, N,N-
DIMETHYLPHTHALATE
DIMETHYL SULFATE
DINITOLMIDE
DINITROBENZENE (ALL ISOMERS)
DINITRO-O-CRESOL
DINITRO-O-TOLUAMIDE, 3,5-
DINITROTOLUENE
DIOXANE, 1,4-
DIOXATHION
DIPHENYL
DIPHENYLAMINE
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE
DIPROPYLENE GYLCOL METHYL ETHER
DIPROPYL KETONE
DIQUAT
DIRECT BLACK 38 (TECHNICAL GRADE)
DIRECT BLUE 6 (TECHNICAL GRADE)
DIRECT BROWN 95
DI-SEC-OCTYL-PHTHALATE
DISULFIRAM
DISULFOTON
DI-TERT-BUTYL-P-CRESOL, 2,6-
DIURON
DIVINYL BENZENE
EMERY
ENDOSULFAN
ENDRIN
ENFLURANE
ENZYMES
EPICHLOROHYDRIN
EPN
EPOXYPROPANE, 1,2-
EPOXY-1-PROPANOL, 2,3-
ESTROGENS, CONJUGATED (INDIRECT)
ETHANE
ETHANETHIOL
ETHANOL
ETHANOLAMINE
ETHINYLOESTRADIOL
ETHION
ETHOXYETHANOL, 2-
ETHOXYETHYL ACETATE, 2-
ETHYL ACETATE
ETHYL ACRYLATE
ETHYL ALCOHOL
ETHYLAMINE
ETHYL AMYL KETONE
ETHYL BENZENE
ETHYL BROMIDE
ETHYL BUTYL KETONE
ETHYL CHLORIDE
ETHYLENE
ETHYLENE CHLOROHYDRIN
ETHYLENEDIAMINE
ETHYLENE DIBROMIDE
ETHYLENE DICHLORIDE
ETHYLENE GLYCOL (VAPOR)
ETHYLENE GLYCOL DINITRATE
ETHYLENE GLYCOL METHYL ETHER
ACETATE
ETHYLENE GLYCOL MONOBUTYL ETHER
ETHYLENE GLYCOL MONOETHYL ETHER
ETHYLENE GLYCOL MONOETHYL ETHER
ACETATE
ETHYLENE GLYCOL MONOMETHYL ETHER
ETHYLENE GLYCOL MONOMETHYL ETHER
ACETATE
ETHYLENE OXIDE
ETHYLENE THIOUREA
ETHYLENIMINE
ETHYL ETHER
ETHYL FORMATE
ETHYLIDENE CHLORIDE
ETHYLIDENE NORBORNENE
ETHYLMORPHOLINE, N-
ETHYL MERCAPTANETHYL METHANE SULPHONATE
ETHYL SILICATE
FENAMIPHOS
FENSULFOTHION
FENTHION
FERBAM
FERROVANADIUM DUST
FIBROUS GLASS DUST

FLUORIDES, AS F
FLUORINE
FLUOROTRICHLOROMETHANE
FONOFOS
FORMALDEHYDE
FORMAMIDE
FORMIC ACID
FORMYLHYDRAZINO)-4(5-NITRO-2-FURYL)THIAZOLE, 2-
FURFURAL
FURFURYL ALCOHOL
GASOLINE
GERMANIUM TETRAHYDRIDE
GLASS, FIBROUS OR DUST
GLUTARALDEHYDE
GLYCERIN MIST
GLYCIDALDEHYDE
GLYCIDOL
GLYCOL MONOETHYL ETHER
GRAIN DUST (OAT, WHEAT, BARLEY)
GRAPHITE (NATURAL)
GRAPHITE (SYNTHETIC)
GUTHION
GYPSUM
HAFNIUM
HALOTHANE
HELIUM
HEMATITE UNDERGROUND MINING
HEPTACHLOR AND HEPTACHLOR EPOXIDE
HEPTANE (N-HEPTANE)
HEPTANONE, 2-
HEPTANONE, 3-
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOHEXANE (LINDANE), Y-
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
HEXACHLORONAPHTHALENE
HEXAFLUOROACETONE
HEXAMETHYLENE DIISOCYANATE
HEXAMETHYL PHOSPHORAMIDE
HEXANE (N-HEXANE)
HEXANE, OTHER ISOMERS
HEXANEDIAMINE, 1,6-
HEXANONE, 2-
HEXONE
HEXYL ACETATE, SEC-
HEXYLENE GLYCOL
HYDRAZINE
HYDRAZINE SULFATE
HYDRAZOBENZENE
HYDROGEN
HYDROGENATED TERPHENYLS
HYDROGEN BROMIDE
HYDROGEN CHLORIDE
HYDROGEN CYANIDE
HYDROGEN FLUORIDE, AS F
HYDROGEN PEROXIDE
HYDROGEN SELENIDE, AS SE
HYDROGEN SULFIDE
HYDROQUINONE
HYDROXY-4-METHYL-2-PENTANONE, 4-
HYDROXYPROPYL ACRYLATE, 2-
INDENE
INDENO(1,2,3-CD)PYRENE
INDIUM & COMPOUNDS, AS IN
IODINE
IODOFORM
IRON DEXTRAN COMPLEX
IRON OXIDE FUME (Fe2O3), AS FE
IRON PENTACARBONYL, AS FE
IRON SALTS, SOLUBLE, AS FE
ISOAMYL ACETATE
ISOAMYL ALCOHOL
ISOBUTYL ACETATE
ISOBUTYL ALCOHOL
ISOOCTYL ALCOHOL
ISOPHORONE
ISOPHORONE DIISOCYANATE
ISOPROPOXYETHANOL
ISOPROPYL ACETATE
ISOPROPYL ALCOHOL
ISOPROPYLAMINE
ISOPROPYLANILINE, N-
ISOPROPYL ETHER
ISOPROPYL GLYCIDYL ETHER (IGE)
ISOPROPYL OIL
KAOLIN
KEPONE
KETENE
LASIOCARPINE
LEAD, INORG. DUST & FUMES, AS PB
LEAD ACETATE
LEAD ARSENATE, AS PbHAsO4
LEAD CHROMATE, AS CR
LEAD PHOSPHATE
LIMESTONE
LINDANE
LITHIUM HYDRIDE
L.P.G. (LIQUIFIED PETROLEUM GAS)
MAGENTA MANUFACTURE
MAGNESITE
MAGNESIUM OXIDE FUME
MALATHION
MALEIC ANHYDRIDE
MALONONITRILEMANGANESE DUST & COMPOUNDS
MANGANESE FUME
MANGANESE CYCLOPENTADIENYL TRI-CARBONYL, AS MN
MANGANESE TETROXIXDE, (AS MN)
MARBLE
MEDROXYPROGESTERONE ACETATE
MEGESTROL ACETATE
MELPHALAN
MERCURY, ALKYL COMPOUNDS, AS HG
MERCURY, ALL FORMS EXCEPT ALKYL VAPOR, AS HG
MERCURY, ARYL & INORGANIC COMPOUNDS, AS HG
MERPHALAN
MESITYL OXIDE
METHACRYLIC ACID
METHANE
METHANETHIOL
METHANOL
METHOMYL
METHOXYCHLOR
METHOXYETHANOL, 2-
METHOXYETHYL ACETATE, 2-
METHOXYPHENOL, 4-
METHYL ACETATE
METHYL ACETYLENE
METHYL ACETYLENE-PROPADIENE MIXTURE (MAPP)
METHYL ACRYLATE
METHYLACRYLONITRILE
METHYLAL
METHYL ALCOHOL
METHYLAMINE
METHYL AMYL ALCOHOL
METHYL N-AMYL KETONE
METHYL ANILINE, N-
METHYLAZOXYMETHANOL
METHYLAZOXYMETHANOL SULFATE
METHYL BROMIDE
METHYL N-BUTYL KETONE
METHYL CELLOSOLVE
METHYL CELLOSOLVE ACETATE
METHYL CHLORIDE
METHYL CHLOROFORM
METHYLCHRYSENE, 5-
METHYL 2-CYANOACRYLATE
METHYLCYCLOHEXANE
METHYLCYCLOHEXANOL
METHYLCYCLOHEXANONE, O-
METHYLCYCLOPENTADIENYL MAN- GANESE TRICARBONYL, AS MN
METHYL DEMETON
METHYLENE BISPHENYL ISOCYANATE
METHYLENE CHLORIDE
METHYLENE BIS(2-CHLOROANILINE) 4,4'-
METHYLENE BIS(4-CYCLO-HEXYLISOCYANATE)
METHYLENE DIANILINE, 4,4-
METHYLENE BIS (2-METHYL-ANILINE), 4,4'-
METHYLENE BIS (N,N-DIMETHYL)
BENZENAMINE, 4,4'-
METHYL ETHYL KETONE
METHYL ETHYL KETONE PEROXIDE
METHYL FORMATE
METHYL HYDRAZINE
METHYL IODIDE
METHYL ISOAMYL KETONE
METHYL ISOBUTYL CARBINOL
METHYL ISOBUTYL KETONE
METHYL ISOCYANATE
METHYL ISOPROPYL KETONE
METHYL MERCAPTAN
METHYL METHACRYLATE
METHYL METHANESULPHONATE
METHYL-1-NITROANTHRAQUINONE, 2-
METHYL-N'-NITRO-N-NITROSO-GUANIDINE, N-
METHYL PARATHION
METHYL PROPYL KETONE
METHYL SILICATE
METHYL STYRENE, ALPHA-
METHYLTHIOURACIL
METRIBUZIN
METRONIDAZOLE
MEVINPHOS
MICA
MICHLER'S KETONE
MINERAL WOOL FIBER
MIREX
MITOMYCIN C
MOLYBDENUM, SOLUBLE COMPOUNDS, AS MO
MOLYBDENUM, INSOLUBLE COMPUNDS, AS MO
MONOCHLOROBENZENE
MONOCHLORODIMETHYL ETHER
MONOCROTALINE
MONOCROTOPHOS
MORPHOLINE
(MORPHOLINOMETHYL)-3-[(5-NITRO-FURFURYLIDENE)AMINO], 2-OXAZO-LIDENONE, 5-
MUSTARD GAS
NAFENOPIN
NALED
NAPHTHA (COAL TAR)
NAPHTHALENE
NAPHTHALENE DIISOCYANATE (NDI)
NAPHTHYLAMINE, ALPHA-
NAPHTHYLAMINE, BETA-
NEON
NICKEL, METAL
NICKEL, INSOLUBLE COMPOUNDS, AS NINICKEL, SOLUBLE COMPOUNDS, AS NI
NICKEL CARBONYL, AS NI
NICKEL SULFIDE ROASTING, FUME & DUST, AS NI
NICOTINE
NIRIDAZOLE
NITRAPYRIN
NITRIC ACID
NITRIC OXIDE
NITRILOTRIACETIC ACID (NTA)
NITROACENAPHTHENE, 5-
NITRO-4-AMINOPHENOL, 2-
NITRO-2-AMINOTOLUENE, 4-
NITROANILINE, P-
NITROBENZENE
NITROBIPHENYL, 4-
NITROCHLOROBENZENE, P-
NITRODIPHENYL, 4-
NITROETHANE
[(NITROFURFURYLIDENE)AMINE]-2-IMIDAZOLIDINONE, 1- [4-(5-NITRO-2-FURYL)-2-THI AZOLYL]ACETAMIDE, N-
NITROGEN
NITROGEN DIOXIDE
NITROGEN MUSTARD
NITROGEN MUSTARD N-OXIDE
NITROGEN TRIFLUORIDE
NITROGLYCERIN (NG)
NITROMETHANE
NITRO-O-ANISIDINE, 5-
NITROPROPANE, 1-
NITROPROPANE, 2-
NITROPYRENES MONO-, DI-, TRI-, TETRA-ISOMERS
NITROSODI-N-BUTYLAMINE, N- (DBN)
NITROSODIETHANOLAMINE, N-(NDELA)
NITROSODIETHYLAMINE, N- (NDEA)
NITROSODIMETHYLAMINE, N-
NITROSODIPHENYLAMINE, P-
NITROSODI-N-PROPYLAMINE, N- (NDPA)
NITROSO-N-ETHYLUREA, N- (ENU)
NITROSOMETHYLETHYLAMINE, N-
NITROSO-N-METHYLUREA, N- (NMU)
NITROSOMETHYLVINYLAMINE, N- (NMVA)
NITROSOMORPHOLINE, N- (NMOR)
NITROSONORNICOTINE, N- (NNN)
NITROSOPIPERIDINE, N- (NPIP)
NITROSOPYRROLIDINE, N- (NPYR)
NITROSOSARCOSINE, N- (NSAR)
NITROTOLUENE, O-
NITROTOLUENE, M-
NITROTOLUENE, P-
NITROCHLOROMETHANE
NITROUS OXIDE
NONANE
NONYLMERCAPTAN, N-
NUISANCE PARTICULATES
OCTACHLORONAPHTHALENE
OCTANE
OIL MIST, MINERAL
OIL ORANGE SS
OSMIUM TETROXIDE, AS OS
OXALIC ACID
OXYDIANILINE, 4,4'-
OXYGEN DIFLUORIDE
OXYMETHOLONE
OZONE
PANAFURAN S
PARAFFIN WAX FUME
PARAQUAT
PARATHION
PARTIC. POLYCYCLIC AROMATIC
HYDROCARBONS (PPAH)
PARTICULATES NOT OTHERWISE
CLASSIFIED (PNOC)
PENTABORANE
PENTACHLORONAPHTHALENE
PENTACHLORONITROBENZENE
PENTACHLOROPHENOL
PENTAERYTHRITOL
PENTANE
PENTANONE, 2-
PERCHLOROETHYLENE
PERCHLOROMETHYL MERCAPTAN
PERCHLORYL FLUORIDE
PERFLUOROISOBUTYLENE
PERLITE
PETROLEUM DISTILLATES
PHENACETIN
PHENACYL CHLORIDE
PHENAZOPYRIDINE
PHENAZOPYRIDINE HYDROCHLORIDE (PAP)
PHENOL
PHENOTHIAZINE
PHENOXYACETIC ACID HERBICIDES
PHENOXYBENZAMINE HYDROCHLORIDE
PHENYL-BETA-NAPHTHYLAMINE, N-
PHENYLENEDIAMINE, M-
PHENYLENEDIAMINE, O-
PHENYLENEDIAMINE, P-
PHENYL ETHER, VAPOR
PHENYL ETHER-BIPHENYL MIXTURE, VAPOR
PHENYLETHYLENE
PHENYL GLYCIDYL ETHER (PGE)
PHENYLHYDRAZINE
PHENYL MERCAPTAN
PHENYLPHOSPHINE
PHENYTOIN (+ SODIUM SALT)
PHORATE
PHOSDRIN
PHOSGENE
PHOSPHINE
PHOSPHORIC ACID
PHOSPHORUS (YELLOW)
PHOSPHORUS OXYCHLORIDE
PHOSPHORUS PENTACHLORIDE
PHOSPHORUS PENTASULFIDE
PHOSPHORUS TRICHLORIDE
PHTHALLIC ANHYDRIDE
PHTHALODINITRILE, M-
PICLORAM
PICRIC ACID
PINDONE
PIPERAZINE DIHYDROCHLORIDE
PIVALYL-1,3-INDANDIONE, 2-
PLASTER OF PARIS
PLATINUM, METAL
PLATINUM, SOLUBLE SALTS, AS PT
POLYBROMINATED BIPHENYLS (PBBs)
POLYCHLORINATED BIPHENYLS (PCBs)
POLYCHLOROBIPHENYLS
POLYTETRAFLUOROETHYLENE DE-COMPOSITION PRODUCTS
PONCEAU 3R
PONCEAU MX
PORTLAND CEMENT
POTASSIUM HYDROXIDE
PRECIPITATED SILICA
PROCARBAZINE
PROCARBAZINE HYDROCHLORIDE
PROGESTERONE (INDIRECT)
PROPANE
PROPANE SULTONE
PROPARGYL ALCOHOL
PROPIOLACTONE, BETA-
PROPIONIC ACID
PROPOXUR (BAYGON)
PROPYL ACETATE, N-
PROPYL ALCOHOL, N-
PROPYLENE
PROPYLENE DICHLORIDE
PROPYLENE GLYCOL DINITRATE
PROPYLENE GLYCOL MONOMETHYL ETHER
PROPYLENE IMINE
PROPYLENE OXIDE
PROPYL NITRATE, N-
PROPYLTHIOURACIL
PROPYNE
PYRETHRUM
PYRIDINE
PYROCATECHOL
QUARTZ
QUINONE
RDX
RESERPINE
RESORCINOL
RHODIUM, METAL
RHODIUM, INSOLUBLE COMPOUNDS, AS RH
RHODIUM, SOLUBLE COMPOUNDS, AS RH
RONNEL
ROSIN CORE SOLDER PYROLYSIS
PRODUCTS, AS FORMALDEHYDE
ROTENONE (COMMERCIAL)
ROUGE
RUBBER SOLVENT (NAPHTHA)
SACCHARIN
SAFROLE
SELENIUM AND COMPOUNDS, AS SE
SELENIUM HEXAFLUORIDE, AS SE
SELENIUM SULFIDE
SESONE
SILANE
SILICA-AMORPHOUS, DIATOMACEOUS
EARTH (UNCALCINED)
SILICA-AMORPHOUS, PRECIPITATED SILICA
SILICA-AMORPHOUS, SILICA, FUME
SILICA-AMORPHOUS, SILICA, FUSED
SILICA-AMORPHOUS, SILICA GEL
SILICA-CRYSTALLINE CRISTOBALITE
SILICA-CRYSTALLINE QUARTZ
SILICA-CRYSTALLINE TRIDYMITE
SILICA-CRYSTALLINE TRIPOLI
SILICA, FUSED
SILICA, FUME
SILICA, GEL
SILICA, PRECIPITATED
SILICON
SILICON CARBIDE
SILICON TETRAHYDRIDE
SILVER, METAL
SILVER, SOLUBLE COMPOUNDS, AS AG
SOAPSTONE
SODIUM AZIDE
SODIUM BISULFITE
SODIUM CYCLAMATE
SODIUM, 2,4-DICHLOROPHEN-
OXYETHYL SULFATE
SODIUM FLUOROACETATE
SODIUM HYDROXIDE
SODIUM METABISULFITE
STARCH
STEARATES
STERIGMATOCYSTIN
STIBINE
STODDARD SOLVENT
STREPTOZOTOCIN (STR)
STRONTIUM CHROMATE, AS CR
STRYCHNINE
STYRENE, MONOMER
SUBTILISINS (PROTEOLYTIC ENZYMES AS 100% PURE CRYSTALLINE ENZYME)
SUCROSE
SULFOTEP
SULFUR DIOXIDE
SULFUR HEXAFLUORIDE
SULFURIC ACID
SULFUR MONOCHLORIDE
SULFUR PENTAFLUORIDE
SULFUR TETRAFLUORIDE
SULFURYL FLUORIDE
SULPROFOS
SYSTOX
T, 2,4,5-
TALC (CONTAINING NO ASBESTOS FIBERS)
TALC (CONTAINING ASBESTOS FIBERS)
TANTALUM, METAL
TANTALUM, OXIDE DUSTS
TEDP
TELLURIUM & COMPOUNDS, AS TE
TELLURIUM HEXAFLUORIDE, AS TE
TEMEPHOS
TEPP (TETRAETHYL DITHIO-PYROPHOSPHATE)
TERPHENYLS
TESTOSTERONE
TETRABROMOETHANE, 1,1,2,2-
TETRACHLORODIBENZO-P-DIOXIN (TCDD), 2,3,7,8,-
TETRACHLORO-1,2-DIFLUOROETHANE1,1,1,2-
TETRACHLORO-2,2-DIFLUOROETHANE1,1,2,2-
TETRACHLOROETHANE, 1,1,1,2-
TETRACHLOROETHANE, 1,1,2,2-
TETRACHLOROETHYLENE
TETRACHLOROMETHANE
TETRACHLORONAPHTHALENE
TETRAETHYL LEAD, AS PB
TETRAHYDROFURAN
TETRAMETHYL LEAD, AS PB
TETRAMETHYL SUCCINONITRILE
TETRANITROMETHANE
TETRASODIUM PYROPHOSPHATE
TETRYL
THALLIUM, SOLUBLE COMPOUNDS, AS TI
THIOACETAMIDE (TAA)
THIOBIS(6-TERT-BUTYL-M-CRESOL), 4,4'-
THIODIANILINE, 4,4'-
THIOGLYCOLIC ACID
THIONYL CHLORIDE
THIOUREA
THIRAM
THORIUM DIOXIDE
TIN, METAL
TIN, OXIDE, & INORGANIC COMPOUNDS, EXCEPT SnH4, AS SN
TIN, ORGANIC COMPOUNDS, AS SN
TIN OXIDE
TITANIUM DIOXIDE
TOLIDINE, O-
TOLUENE
TOLUENE-2,4-DIAMINE
TOLUENE-2,4-DIISOCYANATE (TDI)
TOLUIDINE, O-
TOLUIDINE, M-
TOLUIDINE, P-
TOLUIDINE HYDROCHLORIDE, O-
TOLUOL
TOXAPHENE
TREMOLITE
TREOSULPHAN
TRIBUTYL PHOSPHATE
TRICHLOROACETIC ACID
TRICHLOROBENZENE, 1,2,4-
TRICHLOROETHANE, 1,1,1-
TRICHLOROETHANE, 1,1,2-
TRICHLOROETHYLENE
TRICHLOROFLUOROMETHANE
TRICHLOROMETHANE
TRICHLORONAPHTHALENE
TRICHLORONITROMETHANE
TRICHLOROPHENOL, 2,4,6-
TRICHLOROPHENOXYACETIC ACID, 2,4,5-
TRICHLOROPROPANE, 1,2,3-
TRICHLORO-1,2,2-TRIFLUORO-ETHANE, 1,1,2-
TRICYCLOHEXYLTIN HYDROXIDE
TRIDYMITE
TRIETHANOLAMINE
TRIETHYLAMINE
TRIFLUOROBROMOMETHANE
TRIMELLITIC ANHYDRIDE
TRIMETHYLAMINE
TRIMETHYLANILINE, 2,4,5-TRIMETHYL BENZENE
TRIMETHYL PHOSPHATE
TRIMETHYL PHOSPHITE
TRINITROPHENOL, 2,4,6-
TRINITROPHENYLMETHYL-NITRAMINE, 2,4,6-
TRINITROTOLUENE, 2,4,6- (TNT)
TRIOTHOCRESYL PHOSPHATE
TRIPHENYL AMINE
TRIPHENYL PHOSPHATE
TRIPOLI
TRIS(AZIRIDINYL)-PARA-BENZOQUINONE
TRIS (1-AZIRIDINYL) PHOSPHINE SULFIDE (THIOTEPA)
TRIS(2,3-DIBROMOPROPYL) PHOSPHATE (TRIS)
TRYPAN BLUE (COMMERCIAL GRADE)
TUNGSTEN, INSOLUBLE COMPOUNDS, AS W
TUNGSTEN, SOLUBLE COMPOUNDS, AS W
TURPENTINE
URACIL MUSTARD
URANIUM (NATURAL), SOLUBLE & INSOLUBLE COMPOUNDS, AS U
URETHANE (ETHYL CARBAMATE)
VALERALDEHYDE, N-
VANADIUM, AS V2O5, RESPIRABLE DUST & FUME
VEGETABLE OIL MISTS
VINYL ACETATE
VINYL BENZENE
VINYL BROMIDE
VINYL CHLORIDE
VINYL CYANIDE
VINYL CYCLOHEXENE
VINYL CYCLOHEXENE DIOXIDE
VINYL FLUORIDE
VINYL TOLUENE
VINYLIDENE CHLORIDE
VINYLIDENE FLUORIDE MONOMER
VM & P NAPTHA
WARFARIN
WELDING FUMES (NOC)
WOOD DUST, (CERTAIN HARD WOODS AS BEECH & OAK)
WOOD DUST, SOFT WOOD
WOOD DUST, WESTERN RED CEDAR
XYLENE (O-, M-, P-ISOMERS)
XYLENE-ALPHA,ALPHA'-DIAMINE, M-
XYLIDINE (MIXED ISOMERS)
YTTRIUM METAL & COMPOUNDS, AS Y
ZINC BERYLLIUM SILICATE
ZINC CHLORIDE FUME
ZINC CHROMATES, AS CR
ZINC OXIDE, FUME
ZINC OXIDE, DUST
ZINC STEARATE
ZIRCONIUM COMPOUNDS, AS ZR

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Chemical Safety Manual Contents

Health and Safety Manual Contents

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Office of Health and Safety, Centers for Disease Control and Prevention, 1600 Clifton Road N.E., Mail Stop F05 Atlanta, Georgia 30333, USA Last Modified: 3/22/2001
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