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SECTION 11
Appendices
- MSDS Request Forms, Sample Language for Requesting an MSDS on a Purchase Order, Sample Letter Requesting an MSDS (Coming Soon)
- CDC Manual Guides
- CDC General Memoranda
- Shelf Life of Unstable Chemicals
- Proper Segregation of Chemical Classes
- Form For Hazardous Chemical Inventory
- Spill Control Guidelines
- Guidelines For Proper Glove Selection
- OSHA List of Select Carcinogens
- List of Reproductive Toxins and Highly Acute Toxic Materials
- Documentation of Training Form
- OSHA List of Hazardous Chemicals
- OSHA Standards
- Hazard Communication (29 CFR 1910.1200)
- Occupational Exposure to Hazardous Chemicals in Laboratories
(29 CFR 1910.1450)
Appendix A
- CDC "Request For Material Safety Data Sheet"
- Sample Language for Requesting an MSDS on a Purchase Order
- Sample Letter Requesting an MSDS
Appendix B
- CDC Manual Guides
Appendix C
- CDC General Memoranda
Appendix D
Shelf Life of Unstable Chemicals
Peroxide Hazard on Storage Discard After Three (3) Months Isopropyl ether Divinyl acetylene Vinylidene chloride Potassium metal Sodium amide Peroxide Hazard on Concentration Discard After One (1) Year Ethyl ether Tetrahydrofuran Dioxane Acetal Methyl isobutyl ketone (glyme) Ethylene glycol dimethyl ether Vinyl ethers Dicyclopentadiene Diacetylene Metal acetylene Cumene Tetrahydronaphthalene Cyclohexane t-Butyl alcohol Hazardous to Peroxide Initiation of Polymerization Discard After One (1) Year Styrene Butadiene Tetrafluoroethylene Chlorotrifluoroethylene Vinyl acetylene Vinyl acetate Vinyl chloride Vinyl pyridine Chlorobutadiene (Chloroprene) 9,10-Dihydroanthracene Indene Dibenzocyclopentadiene
Appendix E
Proper Segregation of Chemical Classes
Partial List of Incompatible chemicals
(Toxic Hazards)Substances in the left hand column should be stored and handled so that they cannot possibly accidentally contact corresponding substances in the center column, because toxic materials (right hand column) would be produced.
Arsenical Materials Any Reducing Agent Arsine Azides Acids Hydrogen Azide Cyanides Acids Hydrogen Cyanide Hypochlorites Acids Chlorine or
Hypochlorous AcidNitrates Sulfuric Acid Nitrogen Dioxide Nitric acid Copper, Brass,
Heavy MetalsNitrogen Dioxide Nitrites Acids Nitrous Fumes Phosphorus Caustic Alkalies/
ReducersPhosphine Selenides Reducers Hydrogen Selenide Sulfides Acids Hydrogen Sulfide Tellurides Reducers Hydrogen Telluride Reactive Chemicals
Reactive chemicals are substances which, under certain ambient or induced conditions, enter into violent reactions with spontaneous generation of large quantities of heat, light, gases (flammable and non-flammable), or toxicants that can be destructive to lives and property. Types of reactive chemicals have been loosely categorized:
Explosives
In general, protect explosive substances from shock, elevated temperatures, rapid temperature changes, and other reactive chemicals, Some examples: nitroglycerin, nitrocellulose, and organic peroxides. Many substances, when mixed, are potentially explosive (such as hydrazines and nitric acid).
Oxidizing and Reducing Substances
In many oxidizing and reducing reactions, both agents must be present. In some cases, one or the other substance may create a hazard by coming into contact with a normally innocuous substance. These reactions tend to generate heat and are often explosive, e.g., glycerol and potassium permanganate blended at room temperature for a few minutes react violently producing fire. The following examples of typical oxidizers may:
Increase Rate of Combustion Aluminum nitrate Perchloric acid 60% or less Ammonium persulfate Potassium chlorate Barium chlorate Potassium dichromate Barium peroxide Potassium nitrate Calcium chlorate Potassium persulfate Calcium nitrate Silver nitrate Calcium peroxide Silver nitrite Cupric nitrate Sodium perborate Hydrogen peroxide Sodium perchlorate Lead nitrate Sodium persulfate Lithium hypochlorite Strontium chlorate Lithium peroxide Strontium nitrate Magnesium nitrate Strontium nitrite Magnesium perchlorate Thorium nitrite Magnesium peroxide Uranium nitrate Nickel nitrate Zinc chlorate Nitric acid 70% or less Zinc peroxide Cause Spontaneous Ignition Calcium hypochlorite Sodium chlorite (>40%) Chromic acid Sodium peroxide Hydrogen peroxide (27.5-52%) Sodium permanganate Nitric acid Trichloroisocyanuric acid Potassium bromate Sodium dichloroisocyanurate Potassium permanganate Decompose with Catalyst or Heat Ammonium dichromate Perchloric acid (60-72.5%) Hydrogen peroxide (52-91%) Potassium dichloroisocyanurate Calcium hypochlorite (>50%) Sodium dichloroisocyanurate Cause Explosive Reaction when exposed to Catalyst, Heat, Shock, or Friction Ammonium perchlorate Perchloric acid Ammonium permanganate Potassium superoxide Water Sensitive Substances
These chemicals react with water, steam, and moisture in the air to evolve heat and/or flammable or explosive gases. Isolate water-sensitive substances from other reactive compounds, and store in a cool, waterproof area. Some substances that liberate only hear are: strong acids and bases, acid anhydrides and sulfides. Some substances that liberate flammable gases when exposed to water are: alkali metals, hydrides, nitrites, carbides, and anhydrous metallic salts.
Air Reactive Substances
These materials are capable of rapid release of energy by themselves, as by self-reaction or polymerization, for example white phosphorous. Also included in this category are substances that can be easily ignited by common sources of heat when mixed with air, for example: alkali metals, ammonium nitrate, ammonium perchlorate, ammonium permanganate, benzoyl peroxide, boron hydrides, dinitrobenzene, lithium hydride, sulfur.
Acid Reactive Substances
These chemicals react with acid to evolve heat, flammable and/or explosive gases, and toxicants. Some examples are: alkali metals, hydroxides, carbides, nitrites, arsenic and related elements, cyanides, sulfides, and structural alloys (most metals).
Special Organic Compounds
These compounds are unstable and may decompose spontaneously or through contact with the immediate environment (air, water, and other reactants). Some examples: diazonium compounds, diazomethane, chlorination intermediates, butadiene, nitration intermediates, organic sulfates, polymerization reactions, and highly nitrated compounds.
Pyrophoric Agents
Pyrophoric agents burn when exposed to air. In general, they require absolute protection against air. Examples: phosphorus and activated zinc.
Incompatible Chemicals
The following is a partial listing of incompatible chemicals. A more complete listing may be found in NFPA and various laboratory and chemical reference manuals.
CHEMICAL IS INCOMPATIBLE WITH ACETIC ACID Chromic acid, nitric acid, hydroxyl-containing compounds, ethylene glycol, perchloric acid, peroxides, and permanganates ACETONE Concentrated sulfuric and nitric acid mixtures or chloroform and bases ACETYLENE Copper tubing, halides, silver, mercury and their compounds ALKALI METALS Aluminum, calcium, lithium, magnesium, potassium and sodium with water or chlorinated hydrocarbon, carbon dioxide, halogens AMMONIA, ANHYDROUS Mercury, halogens, calcium hypochlorite, hydrogen fluoride ANILINE Nitric acid and hydrogen peroxide AZIDES Acids BROMINE Ammonia, acetylene, butadiene, butane, hydrogen, sodium carbide, turpentine CHLORATES Ammonium salts, acids, metal powders, sulfur, finely divided organic and combustible materials CHROMIC ACID Acetic acid, alcohol, camphor, flammable liquids, glycerol, naphthalene CHLORINE Ammonia, acetylene, butadiene, benzene and other petroleum fractions, hydrogen, sodium carbides, powdered metals COPPER SALTS Acetylene, hydrogen peroxide CYANIDES Acids ETHYLENEDIAMINE Greater than 3 percent with methylene chloride (explosive) FLAMMABLE LIQUIDS Ammonium nitrate, chromic acid, hydrogen peroxide, halogens, nitric acid, sodium peroxide HYDROCARBONS (Butane, Halogens, chromic acid, peroxides Propane, Benzene) HYDROGEN PEROXIDE Copper, chromium, iron, most metals and their salts, flammable fluids, aniline, and nitromethane HYDROGEN SULFIDE Nitric acid and oxidizing gases IODINE Acetylene, ammonia CHEMICAL IS INCOMPATIBLE WITH MERCURY Acetylene, hydrogen METHYLENE CHLORIDE Greater than 3 percent ethylenediamine (explosive) NITRIC ACID Ac etic, chromic and hydrochloric acids, aniline, carbon, hydrogen sulfide, flammable fluids, or gases which are readily nitrated OXYGEN Oils, grease, hydrogen, flammable liquids, solids, and gases OXALIC ACID Mercury, silver PERCHLORIC ACID Acetic anhydride, alcohol, organic materials, e.g., wood, paper, grease, and oils PHOSPHORUS Air, alkalis, oxygen, reducing agents PHOSPHORUS PENTOXIDE Water SODIUM Carbon dioxide, carbon tetrachloride, water SODIUM PEROXIDE Any oxidizable substances; acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerol, ethylene glycol, ethyl acetate, methanol SULFURIC ACID Potassium chlorate, potassium perchlorate, potassium permanganate
Appendix F
Hazardous Chemical Inventory Form
Appendix G
Appendix H
Guidelines for Proper Glove Selection
(see Personal Protective Equipment Program Manual Appendix)
Appendix I
Osha Select Carcinogens
SUBSTANCE CAS # IARC 1 IARC 2A IARC 2B NTP 1 NTP 2 OSHA ACETALDEHYDE 75-07-0 X ACETAMIDE 60-35-5 X 2-ACETYLAMINOFLUORENE 53-96-3 X X ACRYLAMIDE 79-06-1 X ACRYLONITRILE 107-13-1 X X X ADRIAMYCIN 23214-92-8 X X X AFLATOXINS NONE X X 2-AMINOANTHRAQUINONE
(AAQ)177-79-3 X O-AMINOAZOTOLUENE 97-56-3 X X 4-AMINODIPHENYL 92-67-1 X X X 1-AMINO-2-METHYL-
ANTHRAQUINONE82-28-0 X 2-AMINO-5 (5-NITRO-2-FURYL)
1,3,4-THIADIAZOLE59716-87-9 X 3-AMINO-1,2,
3-TRIAZOLE61-82-5 X X AMITROLE 61-82-5 X X AMOSITE 12172-73-5 X X X ANISIDINE
(O,P-ISOMERS)29191-52-4 X X O-ANISIDINE
HYDROCHLORIDE134-29-2 X ARSENIC &
SOLUBLE
COMPOUNDS, AS7440-38-2 X X X ASBESTOS,
AMOSITE12172-73-5 X X X ASBESTOS,
CHRYSOTILE12001-29-5 X X X ASBESTOS,
CROCODOLITE12001-28-4 X X X ASBESTOS,
OTHER FORMSNONE X X X AURAMINE
MANUFACTURE492-80-8 X AZASERINE 115-02-6 X AZATHIOPRINE 446-86-6 X X BENZAL CHLORIDE 98-87-3 X BENZ(A)ANTHRACENE 56-55-3 X X BENZENE 71-43-2 X X X BENZIDINE 92-87-5 X X X BENZOTRICHLORIDE 106-51-4 X X BENZO(A)PYRENE 50-32-8 X X BENZO(B)
FLUOROANTHENE205-99-2 X X BENZYL CHLORIDE 100-44-7 X BENZYL VIOLET 4B 1694-09-3 X BERYLLIUM AND
COMPOUNDS, AS BE7440-41-7 X " X BISCHLOROETHYL
NITROSOUREA154-93-8 X X BITUMEN 8052-42-4 X 1,3-BUTADIENE 106-99-0 X X 1,4-BUTANEDIOL
DIMETHYLSULFONATE55-98-1 X X BUTYLPHENO-
XYISOPROPYL
CHLOROETHYL SULFITE140-57-8 X B-BUTYROLACTONE 3068-88-0 X CADMIUM
CHLORIDE10108-64-2 X CADMIUM DUSTS
AND SALTS, AS CD7440-43-9 X X CALCIUM
CHROMATE13756-19-0 X CARBON
TETRACHLORIDE56-23-5 X X CHLORAMBUCIL 305-03-3 X X X CHLORDECONE 143-05-0 X X CHLORENDIC ACID 115-28-6 X CHLORINATED
CAMPHENE8001-35-2 X CHLORINATED
PARAFFINS108171-26-2 X 1-CHLORO-2,3-EPOXYPROPANE 106-89-8 X X 1-(2-CHLOROETHYL)-
3-CYCLOHEXYL-
1-NITROSOUREA13010-47-4 X X CHLOROETHYLENE 75-01-4 X X X CHLOROFORM 67-66-3 X X BIS(CHLORO-
METHYL)ETHER542-88-1 X X X CHLOROMETHYL
METHYL ETHER107-30-2 X X X 3-CHLORO-2-METHYL
PROPENE563-47-3 X 4-CHLORO-O-
PHENYLDIAMINE95-83-0 X X 4-CHLORO-TOLUIDINE 95-69-2 X 2-CHLOROPHENOL 95-57-8 X 3-CHLOROPHENOL 108-43-0 X 4-CHLOROPHENOL 106-48-9 X CHROMIUM (VI)
COMPOUNDS, AS CR,
WATER SOLUBLENONE X X X CHROMIUM (VI)
COMPOUNDS, AS CR, CERTAIN
WATER INSOLUBLENONE X X X CHROMIUM TRIOXIDE 1333-82-0 X CHRYSOTILE 12001-29-5 X X X CISPLATIN 15663-27-1 X CITRUS RED NO. 2 6358-53-8 X COAL TAR
PITCH VOLATILES65996-93-2 X X COKE OVEN EMISSIONS NONE X X X P-CRESIDINE 120-71-8 X X CRISTOBALITE 14464-46-1 X CROCIDOLITE 12001-28-4 X X X CUPFERRON 135-20-6 X CYCASIN 14901-08-7 X CYCLOPHOSPHAMIDE 50-18-0 X X X DDT (DICHLORODIPHENYL
-TRICHLORETHANE)50-29-3 X X DACARBAZINE 4342-03-4 X X DAUNOMYCIN 20830-31-3 X N,N'-DIACETYLBENZIDINE 613-35-4 X 2,4-DIANIMOANISOLE 615-05-4 X 2,4-DIAMINOANISOLE
SULFATE39156-41-7 X X 4,4'-DIAMINODIPHENYL
ETHER101-80-4 X X 2,4-DIAMINOTOLUENE 95-80-7 X X DIBENZ(A,H)ACRIDINE 226-36-8 X X DIBENZ(A,J)ACRIDINE 224-42-0 X X DIBENZA(A,
H)ANTHRACENE53-70-3 X X 7H-DIBENZO(C,
G)CARBAZOLE194-59-2 X X DIBENZO(A,E)PYRENE 192-65-4 X X DIBENZO(A,
H)PYRENE189-64-0 X X DIBENZO(A,I)PYRENE 189-55-9 X X 1,2-DIBROMO-3-
CHLOROPROPANE96-12-8 X X 1,2-DIBROMOETHANE 106-93-4 X X 3,3'-DICHLOROBENZIDINE 91-94-1 X X X 3,3'-DICHLORO-4,4'-
DIAMINODIPHENYL ETHER28434-86-8 X X 1,2-DICHLOROETHANE 107-06-2 X X DICHLOROMETHANE 75-09-2 X X 2,4-DICHLOROPHENYL-P-
NITROPHENYL ETHER1836-75-5 X X 1,3-DICHLOROPROPENE 542-75-6 X X DIEPOXYBUTANE 1464-53-5 X X DIETHYLDITHIOCARBAMIC
ACID 2-CHLORALLYL
ESTER95-06-7 X X DI(2-ETHYLHEXYL)PHTHALATE 117-81-7 X X 1,2-DIETHYLHYDRAZINE 1615-80-1 X DIETHYLSTILBESTROL 56-53-1 X X X DIETHYL SULFATE 64-67-5 X X DIGLYCIDYL RESORCINOL
ETHER101-90-6 X X DIHYDROSAFROLE 94-58-6 X 3,3'-DIMETHOXYBENZIDINE 119-90-4 X 4-DIMETHYLAMINOAZO
-BENZENE60-11-7 X X X 3,3'-DIMETHYLBENZIDENE 119-93-7 X X DIMETHYL CARBOMYL
CHLORIDE79-44-7 X X 1,1-DIMETHYLHYDRAZINE 57-14-7 X X 1,2-DIMETHYLHYDRAZINE 540-73-8 X N,N-DIMETHYL
-NITROSOAMINE65-72-9 X X X DIMETHYL SULFATE 77-78-1 X X 1,4-DIOXANE 123-91-1 X X DIRECT BLACK 38
(TECHNICAL GRADE)1937-37-7 X DIRECT BLUE 6
(TECHNICAL GRADE)2602-46-2 X DI-SEC-OCTYL-
PHTHALATE117-81-7 X X X X EPICHLOROHYDRIN 106-89-8 X X 1,2-EPOXYPROPANE 75-56-9 X ESTROGENS, CONJUGATED
(INDIRECT)NONE X ETHYL ACRYLATE 140-88-5 X X ETHYLENE DIBROMIDE 106-34-4 X X ETHYLENE DICHLORIDE 107-06-2 X X ETHYLENE OXIDE 75-21-8 X X ETHYLENE THIOUREA 96-45-7 X X ETHYLENIMINE 151-56-4 X ETHYL METHANE
SULPHONATE62-50-0 X FORMALDEHYDE 50-00-0 X X X 2-(2-FORMYLHYDRAZINO)-4-
(5-NITRO-2-
FURYL)THIAZOLE3570-75-0 X GLYCIDALDEHYDE 765-34-4 X HEMATITE UNDERGROUND
MININGNONE X HEXACHLOROBENZENE 118-74-1 X X HEXAMETHYL
PHOSPHORAMIDE680-31-9 X X HYDRAZINE 302-01-2 X X HYDRAZINE
SULFATE10034-93-2 X HYDRAZOBENZENE 122-66-7 X INDENO(1,2,3-CD)PYRENE 193-30-5 X X IRON DEXTRAN
COMPLEX9004-66-4 X X ISOPROPYL OIL NONE X KEPONE 143-50-0 X X LASIOSCARPINE 303-34-4 X LEAD, INORGANIC DUSTS
AND FUMES, AS PB7439-92-1 X LEAD ACETATE 301-04-2 X LINDANE 58-89-9 X MAGENTA MANUFACTURE 632-99-5 X MELPHALAN 148-82-3 X X MERPHALAN 531-76-0 X METHYLAZOXYMETHANOL 590-96-5 X METHYLAZOXYMETHANOL
SULFATE592-62-1 X 5-METHYLCHRYSENE NONE X METHYLENE CHLORIDE 75-09-2 X 4,4'-METHYLENE
BIS(2-CHLOROANILINE)101-14-4 X X 4,4'-METHYLENE
DIANILINE101-77-9 X X 4,4'-METHYLENE
BIS(2-METHYLANILINE)838-88-0 X 4,4'-METHYLENE
BIS(N,N-DIMETHYL
BENZENAMINE)101-61-1 X METHYL
METHANESULPHONATE66-27-3 X 2-METHYL-1-
NITROANTHRAQUINONE129-15-7 X N-METHYL-N'-NITRO-
N-NITROSOQUANIDINE70-25-7 X METHYLTHIOURACIL 56-04-2 X METRONIDAZOLE 443-48-1 X X MICHLER'S KETONE 90-94-8 X MIREX 2385-85-5 X X MITOMYCIN C 50-07-7 X MONOCROTALINE 315-22-0 X MUSTARD GAS 505-60-2 X X X NAFENOPIN 3771-19-5 X NAPHTHA (COAL TAR) 8030-30-6 X ALPHA-NAPHTHYLAMINE 134-32-7 X BETA-NAPHTHYLAMINE 91-59-8 X X X NICKEL, METAL 7440-02-0 X X NICKEL, INSOLUBLE
COMPOUNDS, AS NI7440-02-0 X X NICKEL, SOLUBLE
COMPOUNDS, AS NI7440-02-0 X X NICKEL CARBONYL,
AS NI7440-02-0 X NICKEL SULFIDE
ROASTING, FUMENONE X NIRIDAZOLE 61-57-4 X NITRILOTRIACETIC
ACID (NTA)139-13-9 X 5-NITROACENAPHTHENE 602-87-9 X 4-NITROBIPHENYL 92-93-3 X 1-[(NITROFURFURYLIDENE)AMINO]-
2-IMIDAZOLIDINONE555-84-0 X N-[4-(5-NITRO-2-FURYL)
-2-THIAZOLYL] ACETAMIDE531-82-8 X NITROGEN MUSTARD 51-75-2 X X NITROGEN MUSTARD N-OXIDE 302-70-5 X 5-NITRO-O-ANISIDINE 99-59-2 X 2-NITROPROPANE 79-46-9 X N-NITROSODI-N
-BUTYLAMINE (DBN)924-16-3 X X N-NITROSODIETHANOLAMINE
(NDELA)1116-54-7 X X N-NITROSODIETHYLAMINE
(NDEA)55-18-5 X X N-NITROSODIMETHYLAMINE 62-75-9 X X X P-NITROSODIPHENYLAMINE 156-10-5 X N-NITROSODI-N-
PROPYLAMINE (NDP)621-64-7 X X N-NITROSO-N-
ETHYLUREA (ENU)759-73-9 X N-NITROSOMETHYLETHYLAMINE 10595-95-6 X N-NITROSO-N-
METHYLUREA (NMU)684-93-5 X X N-NITROSOMETHYLVINYLAMINE
(NMVA)13256-13-8 X X N-NITROSOMORPHOLINE
(NMOR)59-89-2 X X N'-NITROSONORNICOTINE
(NNN)16543-55-8 X X N-NITROSOPIPERIDINE
(NPIP)100-75-4 X X N-NITROSOPYRROLIDINE
(NPYR)930-55-2 X X N-NITROSOSARCOSINE
(NSAR)13256-22-9 X X OIL ORANGE SS 2646-17-5 X 4,4'-OXYDIANILINE 101-80-4 X OXYMETHOLONE 434-07-1 X PANFURAN S 794-93-4 X PARTICULATE POLYCYCLIC
AROMATIC HYDROCARBONS65995-93-2 X X PERCHLOROETHYLENE 127-18-4 X PHENACETIN 66-44-2 X X PHENAZOPYRIDE 94-78-0 X PHENAZOPYRIDE
HYDROCHLORIDE136-40-3 X X PHENOXYACETIC
ACID HERBICIDESNONE X PHENOXYBENZAMINE
HYDROCHLORIDE63-92-3 X X PHENYTOIN
(+ SODIUM SALTS)57-41-0 X X POLYBROMINATED
BIPHENYLS (PBBs)36355-01-8 X X POLYCHLORINATED
BIPHENYLS (PCBs)1336-36-3 X X PONCEAU MS 3761-53-3 X PONCEAU 3R 65997-15-1 X PROCARBAZINE 671-16-9 X PROCARBIZINE
HYDROCHLORIDE366-70-1 X X PROGESTERONE
(INDIRECT)NONE X PROPANE SULTONE 1120-71-4 X X BETA-PROPIOLACTONE 57-57-8 X X X PROPYLENE IMINE 75-55-8 X PROPYLENE OXIDE 75-56-9 X X PROPYLTHIOURACIL 51-52-5 X X X QUARTZ 14808-60-7 X RESERPINE 50-55-5 X SACCHARIN 81-07-2 X X SAFROLE 94-59-7 X X SELENIUM SULFIDE 7446-34-6 X SILICA-CRYSTALLINE,
CRISTOBALITE14464-46-1 X SILICA-CRYSTALLINE,
QUARTZ14808-60-7 X SILICA-CRYSTALLINE,
TRIDYMITE15468-32-3 X SILICA-CRYSTALLINE,
TRIPOLI1317-95-9 X STERIGMATOCYSTIN 10048-13-2 X STR valign=bottom EPTOZOTOCIN 18883-66-4 X X STR valign=bottom ONTIUM CHROMATE, AS CR 7789-06-2 X STYRENE, MONOMER 100-42-5 X TALC (CONTAINING
ASBESTOS FIBERS)NONE X X X 2,3,7,8-TETRACHLORODIBENZO
-P-DIOXIN1746-01-6 X X TETRACHLOROETHYLENE 127-18-4 X X TETRACHLOROMETHANE 56-23-5 X X THIOACETAMIDE (TTA) 62-55-5 X X 4,4'-THIODIANALINE 139-65-1 X THIOUREA 62-56-6 X X THORIUM DIOXIDE NONE X O-TOLIDINE 119-93-7 X X TOLUENE-2,
4-DIAMINE95-80-7 X X TOLUENE-2,
4-DIISOCYANATE (TDI)584-84-9 X X O-TOLUIDINE 95-53-4 X X O-TOLUIDINE
HYDROCHLORIDE636-21-5 X TOXAPHENE 8001-35-2 X X TREMOLITE 1332-21-4 X X X TREOSULPHAN 299-75-2 X TRICHLOROMETHANE 67-66-3 X X 2,4,6-TRICHLOROPHENOL 88-06-6 X TRIDYMITE 15468-32-3 X TRIPOLI 1317-95-9 X TR valign=bottom IS(1-AZIRIDINYL)
PHOSPHINE
SULFIDE52-24-4 X X TR valign=bottom IS(2,3-DIBROMOPROPYL)
PHOSPHATE126-72-7 X X TRYPAN BLUE
(COMMERCIAL GRADE)72-57-1 X URACIL MUSTARD 66-75-1 X URETHANE (ETHYL
CARBAMATE)51-79-6 X X VINYL BENZENE 100-42-5 X VINYL BROMIDE 593-60-2 X VINYL CHLORIDE 75-01-4 X X X VINYL CYANIDE 107-13-1 X X X ZINC BERYLLIUM
SILICATE39413-47-3 X X ZINC CHROMATES, AS CR NONE X
Appendix J
Reproductive Toxins and Highly Acute Toxic Materials
Reproductive Toxins
Acrylonitr ile
Aniline
Arsenic and its compounds
Benzene
Benzo(a)pyrene
Beryllium
Boric acid (Boron)
Cadmium and its compounds
Carbon monoxide
Chlordecone (Kepone)
Chloroform
Chloroprene
Dibromochloropropane (DBCP)
Dichlorobenzene
1,1-Dichloroethane
Dichloromethane
Dioxane
Epichlorohydrin
Ethylene Dibromide
Ethylene Dichloride
Ethylene Oxide
Fluorocarbons
Formaldehyde
Formamides
Lead (Organic)
Manganese and its compounds
Mercury and its compounds (Inorganic)
Methyl n-butyl ketone
Methyl chloroform
Methyl ethyl ketone (MEK)
Nitrogen Dioxide
Ozone
Platinum and its compounds
Polybrominated biphenyls (PBB)
Polychlorinated bipenyls (PCB)
Selenium and its compounds
Styrene
Tellurium and its compounds
Tetr achloroethylene
Thallium and its compounds
Toluene
Toluene-2,4-diisocyanate
o-Toluidine
Trichloroethylene
Vinyl chloride
Vinylidene chloride
XyleneHighly Acute Toxic Materials
Abrin
N-Acetoxy-2-acetylaminofluorene
Actinomycin D
Aldicarb
o-Aminoazobenzene
2-Aminofluorene
Anabasine
Apholate
Arsenious Acid, Monosodium Salt
Arsenic tr ioxide
Atr opine
N,N-bis(2-chloromethyl)-2-Naphthylamine
Bromoethyl methanesulfonate
1,4-Butanediol dimethylsulfonate
Canthardin
2-chloro-4-Dimethyl-amino-6-methylpyrlmidine
Cyanogen Bromide
Diazomethane
Digalen
Digifolin
Digoxin
7,12-Dimethylbeze[a]anthracene
3,3'-Dimethoxybenzidine
3,3'-Dimethylbenzidine
Dimetthylethylenimine
1,2-Dimethylhydrazine
3,3'-Dimethoxybenzidine, dihydrochloride
1,4-Dinitr osopoperazine
Duboisine
Ethionine
Ethylenimine
Ethylene glycol dinritr ate
Ethyl methanesulfonate
Fluroactetic acid
Gitalin
Heroin
Hexaaethyl tetr aphosphate
Hydrazoic acid
Hydrocyanic acid
N-Hydroxy-2-acetylaminofluorene
Hyoscyamine
Inorganic arsenic
Isobenzan
K-Str ophanthin
Lanatoside
Lysergic acid diethylamide
3-Methylcholanthrene
Methyl chloromethyl ether
4,4'-Methylene bis-(2-chloraniline)
Methylhydrazine
Methyl methanesulfonate
Nicotine salicylate
N-[4-(5-Nitr o-2-furyl)-2-thiazoly]-formamide
Nitr oglycerin
N-Nitr oquinoline-1-oxide
N-Nitr osodimethylamine
N-Nitr oso-N-methylurethane 2H-1,3,2-oxazaphosphorine ,2[bis(2-chloroethyl) Amino]tetr ahydro-,2 oxide
Pantopon
Parathion
Paroxon
Phosphine
Phosphorodithioic acid
Phosphorous (Yellow)
Propylenimine
2-propyl-piperidine
Ricin
Scopolamine
Sarin
Sodium Azide
Sodium Selenate
Sulfotepp
Tabun
Tepp
2,3,7,8-Tetr achlorodibenzofuran
Thimet
m-Toluenediamine
Uracil mustard
Appendix L
OSHA List of Hazardous Chemicals
ACETALDEHYDE
ACETAMIDE
ACETIC ACID
ACETIC ANHYDRIDE
ACETONE
ACETONItr ILE
ACETYLAMINOFLUORENE, 2-
ACETYLENE
ACETYLENE DICHLORIDE
ACETYLENE TETRABROMIDE
ACETYLSALICYLIC ACID (ASPIRIN)
ACROLEIN
ACRYLAMIDE
ACRYLIC ACID
ACRYLONITRILE
ACTINOMYCIN D
ADRIAMYCIN
AFLATOXINS
ALDRIN
ALLYL ALCOHOL
ALLYL CHLORIDE
ALLYL GLYCIDYL ETHER (AGE)
ALLYL PROPYL DISULFIDE
ALUMINA
ALUMINUM, METAL DUST, AS AL
ALUMINUM, PYRO POWDERS, AS AL
ALUMINUM, SOLUBLE SALTS, AS AL
ALUMINUM, WELDING FUMES, AS AL
ALUMINUM, ALKYLS, NOT OTHERWISE
CLASSIFIED, AS AL
ALUMINUM OXIDE, AS AL
AMINOANTHRAQUINONE (AAQ), AMINOAZOTOLUENE, O-
AMINOBIPHENYL, 4-
AMINOETHANOL, 2-
AMINO-2-METHYLANTHRAQUINONE, 1-
AMINO-5-(5-NITRO-2-FURYL)- -1,
3,4-THIADIADIAZOLE, 2-
AMINOPYRIDINE, 2-
AMINO-1,2,4-TRIAZOLE, 3-
AMITROLE
AMMONIA
AMMONIUM CHLORIDE FUME
AMMONIUM PERFLUOROOCTANOATE
AMMONIUM SULFAMATE
AMOSITE
AMYL ACETATE, N-
AMYL ACETATE, SEC-
ANILINE & HOMOLOGUES
ANISIDINE (O-,P-ISOMERS)
ANISIDINE HYDROCHLORIDE, O-
ANTIMONY & COMPOUNDS, AS SB
ANTIMONY TRIOXIDE, HANDLING AND USE, AS SB
ANTIMONY TRIOXIDE, PRODUCTION
ANTU
ARAMITE
ARGON
ARSENIC & SOLUBLE COMPOUNDS, AS AS
ARSENIC TRIOXIDE PRODUCTION
ARSINE
ASBESTOS, AMOSITE
ASBESTOS, CHRYSOTILE
ASBESTOS, CROCIDOLITE
ASBESTOS, OTHER FORMS
ASPHALT (PETROLEUM) FUMES
ATRAZINE
AURAMINE MANUFACTURE
AZASERINE
AZATHIOPRINE
AZINPHOS-METHYL
AZO DYES
BARIUM, SOLUBLE COMPOUNDS, AS BA
BARIUM SULFATE
BAYTEX (FENTOIN)
BEECH WOOD DUST
BENOMYL
BENZAL CHLORIDE
BENZ(A)ANTHRACENE
BENZENE
BENZIDINE
BENZOQUINONE, P-
BENZOTRICHLORIDE
BENZOYL PEROXIDE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZYL CHLORIDE
BENZYL VIOLET 4B
BERYLLLIUM AND COMPUNDS, AS BE
BIPHENYL
BISCHLOROETHYL NITROSOUREA (BCNU)
BISMUTH TELLURIDE (UNDOPED)
BISMUTH TELLURIDE (SE-Doped)
BITUMEN
BORATES, TETRA, SODIUM SALTS, ANHYDROUS
BORATES, TETRA, SODIUM SALTS, DECAHYDRATE
BORATES, TETRA, SODIUM SALTS, PENTAHYDRATE
BORON OXIDE
BORON TRIBROMIDE
BORON TRIFLUORIDE
BROMACIL
BROMINE
BROMINE PENTAFLUORIDE
BROMOCHLOROMETHANE
BROMOFORM
BUTADIENE, 1,3-
BUTANE
BUTANEDIOL DIMETHYSULFONATE, 1,4-
BUTANETHIOL
BUTANONE, 2-
BUTOXYETHANOL, 2-
BUTYL ACETATE, N-
BUTYL ACETATE, SEC-
BUTYL ACETATE, TERT-
BUTYL ACRYLATE, N-
BUTYL ALCOHOL, N-
BUTYL ALCOHOL, SEC-
BUTYL ALCOHOL, TERT-
BUTYLAMINE, N-
BUTYL CHROMATE, AS CR03, TERT-
BUTYL GLYCIDYL ETHER (BGE), N-
BUTYL LACTATE, N-
BUTYL MERCAPTAN
BUTYLPHENOL, O-SEC-
BUTYLPHENOXYISOPROPYL CHLORO-
ETHYL SULFITE (ARAMITE)
BUTYLTOLUENE, P-TERT-
BUTYROLACTONE, BETA-
CADMIUM CHLORIDE
CADMIUM DUSTS & SALTS, AS CD
CADMIUM OXIDE FUME, AS CD
CADMIUM OXIDE PRODUCTION
CALCIUM CARBONATE
CALCIUM CHROMATE, AS CR
CALCIUM CYANAMIDE
CALCIUM CYCLAMATE
CALCIUM HYDROXIDE
CALCIUM OXIDE
CALCIUM SILICATE
CALCIUM SULFATE
CAMPHOR, SYNTHETIC
CAPROLACTAM DUST
CAPROLACTAM VAPOR
CAPTAFOL
CAPTAN
CARBARYL
CARBOFURAN
CARBON BLACK
CARBON DIOXIDE
CARBON DISULFIDE
CARBON MONOXIDE
CARBON TETRABROMIDE
CARBON TETRACHLORIDE
CARBONYL CHLORIDE
CARBONYL FLUORIDE
CATECHOL
CELLULOSE (PAPER FIBER)
CESIUM HYDROXIDE
CHLORAMBUCIL
CHLORAMPHENICOL
CHLORDANE
CHLORDECONE (KEPONE)
CHLORENDIC ACID
CHLORINATED CAMPHENE
CHLORINATED DIPHENYL OXIDE
CHLORINATED PARAFFINS
CHLORINE
CHLORINE DIOXIDE
CHLORINE TRIFLUORIDE
CHLORNAPHAZINE
CHLOROACETALDEHYDE
CHLOROACETONE
CHLOROACETOPHENONE, ALPHA-
CHLOROACETYL CHLORIDE
CHLOROBENZENE
CHLOROBENZILATE
CHLOROBENZYLIDENE MALONO-NITRILE, O-
CHLOROBROMOMETHANE
CHLORO-1,3-BUTADIENE, 2-
CHLORODIFLUOROMETHANE
CHLORO,2,3-EPOXY-PROPANE, 1-
CHLORODIPHENYL (42% CHLORINE)
CHLORODIPHENYL (54% CHLORINE)
CHLOROETHANE
CHLOROETHANOL, 2-
CHLOROETHYL)-3-CYCLOHEXYL-1-
NITROSOUREA, 1-(2-
CHLOROETHYLENE
CHLOROFLUOROMETHANE
CHLOROFORM
(CHLOROMETHYL) ETHER, BIS-
CHLOROMETHYL METHYL ETHER
CHLORO-2-METHYLPROPENE, 3-
CHLORO-1-NITROPROPANE, 1-
CHLORO-O-PHENYLENEDIAMINE, 4-
CHLORO-O-TOLUIDINE, 4-
CHLOROPENTAFLUOROETHANE
CHLOROPHENOL, 2-
CHLOROPHENOL, 3-
CHLOROPHENOL, 4-
CHLOROPICRIN
CHLOROPRENE, BETA-
CHLOROPROPIONIC ACID
CHLOROSTYRENE, O-
CHLOROTOLUENE, O-
CHLORO-6-(TRICHLOROMETHYL) PYRIDINE, 2-
CHLORPYRIFOS
CHROMATES, ALKALINE, AS CR
CHROMIC ACID AND CHROMATES, AS CRO3
CHROMITE ORE PROCESSING (CHROMATE), AS CR
CHROMIUM (II) COMPOUNDS, AS CR
CHROMIUM (III) COMPOUNDS, AS CR
CHROMIUM (VI) COMPOUNDS, AS CR, WATER SOLUBLE
CHROMIUM (VI) COMPOUNDS, AS CR, CERTAIN WATER INSOLUBLE
CHROMIUM METAL
CHROMIUM TRIOXIDE
CHROMYL CHLORIDE
CHRYSENE
CHRYSOTILE
CISPLATIN
CITRUS RED NO. 2
CLOPIDOL
COAL DUST
COAL TAR PITCH VOLATILES, AS BENZENE SOLUBLES
COBALT, METAL DUST & FUME, AS CO
COBALT CARBONYL, AS CO
COBALT HYDROCARBONYL, AS CO
COKE OVEN EMISSIONS
COPPER FUME
COPPER DUSTS & MISTS, AS CU
COTTON DUST, RAW
CRESIDINE, P-
CRESOL, ALL ISOMERS
CRISTOBALITE
CROCIDOLITE
CROTONALDEHYDE
CRUFOMATE
CUMENE
CUPFERRON
CYANAMIDE
CYANIDE, CALCIUM, AS CN
CYANIDE, POTASSIUM, AS CN
CYANIDE, SODIUM, AS CN
CYANOGEN
CYANOGEN CHLORIDE
CYCASIN
CYCLAMATES
CYCLOHEXANE
CYCLOHEXANOL
CYCLOHEXANONE
CYCLOHEXENE
CYCLOHEXYLAMINE
CYCLONITE
CYCLOPENTADIENE
CYCLOPENTANE
CYCLOPHOSPHAMIDE
CYHEXATIN
D, 2,4-
DDT (DICHLORODIPHENYLTRI-CHLOROETHANE)
DACARBAZINE
DAUNOMYCIN
DECABORANE
DEMETON-METHYL
DEMETON (SYSTOX)
DIACETONE ALCOHOL
DIACETYLBENZIDINE, N,N'-
DIAMINOANISOLE, 2,4-
DIAMINOANISOLE SULFATE, 2,4-
DIAMINODIPHENYL ETHER, 4,4'-
DIAMINODIPHENYLMETHANE, 4,4'-
DIAMINOETHANE, 1,2-
DIAMINOTOLUENE, 2,4-
DIATOMACEOUS EARTH
DIAZINON
DIAZOMETHANE
DIBENZ(A,H)ACRIDINE
DIBENZ(A,J)ACRIDINE
DIBENZ(A,H)ANTHRACENE
DIBENZO(C,G)CARBAZOLE, 7H-
DIBENZO(A,E)PYRENE
DIBENZO(A,H)PYRENE
DIBENZO(A,I)PYRENE
DIBORANE
DIBROM
DIBROMO-3-CHLOROPROPANE (DBCP), 1,2-
DIBROMOETHANE, 1,2-
DIBUTYLAMINOETHANOL, 2-N-
DIBUTYL PHENYL PHOSPHATE
DIBUTYL PHTHALATE
DICHLOROACETYLENE
DICHLOROBENZENE, O-
DICHLOROBENZENE, P-
DICHLOROBENZIDINE, 3,3'-
DICHLORO-4,4'-DIAMINODIPHENYL ETHER, 3,3'-
DICHLORODIFLUOROMETHANE
DICHLORO-5,5-DIMETHYL HYDAN-TOIN, 1,3-
DICHLORODIPHENYL-TRICHLORO-ETHANE
DICHLOROETHANE, 1,1-
DICHLOROETHANE, 1,2-
DICHLOROETHYLENE, 1,1-
DICHLOROETHYLENE, 1,2-
DICHLOROETHYL ETHER
DICHLOROFLUOROMETHANE
DICHLOROMETHANE
DICHLORO-1-NITROETHANE, 1,1-
DICHLOROPHENOXY ACETIC ACID, 2,4-
DICHLOROPHENYL-P-NITROPHENYL ETHER, 2,4- (TOK)
DICHLOROPROPANE, 1,2-
DICHLOROPROPENE,1,3-
DICHLOROPROPIONIC ACID, 2,2-
DICHLOROTETRAFLUOROETHANE
DICHLORVOS
DICROTOPHOS
DICYCLOPENTADIENE
DICYCLOPENTADIENYL IRON
DIELDRIN
DIEPOXYBUTANE
DIETHANOLAMINE
DIETHYLAMINE
DIETHYLAMINOETHANOL, 2-
DIETHYLCARBAMOYL CHLORIDE
DIETHYLDITHIOCARBAMIC ACID 2-CHLORALLYL-ESTER
DIETHYLENE TRIAMINE
DIETHYL ETHER
DI(2-ETHYLHEXYL)PHTHALATE
DIETHYLHYDRAZINE, 1,2-
DIETHYL KETONE
DIETHYL PHTHALATE
DIETHYLSTILBESTROL
DIETHYL SULFATE
DIFLUORODIBROMOMETHANE
DIGLYCIDYL ETHER (DGE)
DIGLYCIDYL RESORCINOL ETHER
DIHYDROSAFROLE
DIHYDROXYBENZENE
DIISOBUTYL KETONE
DIISOPROPYLAMINE
DIMETHOXYBENZIDINE, 3,3'-
DIMETHOXYMETHANE
DIMETHYL ACETAMIDE, N,N-
DIMETHYLAMINE
DIMETHYLAMINOAZOBENZENE, 4-
DIMETHYLAMINOBENZENE
(DIMETHYLAMINO)METHYLIMINO]-5-[2-5-NITRO-2-FURYL)VINYL]-1,3, 4-OXADIAZOL, TRANS-2
DIMETHYLANILINE
DIMETHYLBENZENE
DIMETHYLBENZIDINE, 3,3-
DIMETHYL CARBAMOYL CHLORIDE
DIMETHYL-1,2-DIBROMO-2-DI-CHLOROETHYL
PHOSPHATE
DIMETHYL ETHER
DIMETHYL ETHYL AMINE, N,N-
DIMETHYLFORMAMIDE
DIMETHYL-4-HEPTANONE, 2,6-
DIMETHYLHYDRAZINE, 1,1-
DIMETHYLHYDRAZINE, 1,2-
DIMETHYLNITROSOAMINE, N,N-
DIMETHYLPHTHALATE
DIMETHYL SULFATE
DINITOLMIDE
DINITROBENZENE (ALL ISOMERS)
DINITRO-O-CRESOL
DINITRO-O-TOLUAMIDE, 3,5-
DINITROTOLUENE
DIOXANE, 1,4-
DIOXATHION
DIPHENYL
DIPHENYLAMINE
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE
DIPROPYLENE GYLCOL METHYL ETHER
DIPROPYL KETONE
DIQUAT
DIRECT BLACK 38 (TECHNICAL GRADE)
DIRECT BLUE 6 (TECHNICAL GRADE)
DIRECT BROWN 95
DI-SEC-OCTYL-PHTHALATE
DISULFIRAM
DISULFOTON
DI-TERT-BUTYL-P-CRESOL, 2,6-
DIURON
DIVINYL BENZENE
EMERY
ENDOSULFAN
ENDRIN
ENFLURANE
ENZYMES
EPICHLOROHYDRIN
EPN
EPOXYPROPANE, 1,2-
EPOXY-1-PROPANOL, 2,3-
ESTROGENS, CONJUGATED (INDIRECT)
ETHANE
ETHANETHIOL
ETHANOL
ETHANOLAMINE
ETHINYLOESTRADIOL
ETHION
ETHOXYETHANOL, 2-
ETHOXYETHYL ACETATE, 2-
ETHYL ACETATE
ETHYL ACRYLATE
ETHYL ALCOHOL
ETHYLAMINE
ETHYL AMYL KETONE
ETHYL BENZENE
ETHYL BROMIDE
ETHYL BUTYL KETONE
ETHYL CHLORIDE
ETHYLENE
ETHYLENE CHLOROHYDRIN
ETHYLENEDIAMINE
ETHYLENE DIBROMIDE
ETHYLENE DICHLORIDE
ETHYLENE GLYCOL (VAPOR)
ETHYLENE GLYCOL DINITRATE
ETHYLENE GLYCOL METHYL ETHER
ACETATE
ETHYLENE GLYCOL MONOBUTYL ETHER
ETHYLENE GLYCOL MONOETHYL ETHER
ETHYLENE GLYCOL MONOETHYL ETHER
ACETATE
ETHYLENE GLYCOL MONOMETHYL ETHER
ETHYLENE GLYCOL MONOMETHYL ETHER
ACETATE
ETHYLENE OXIDE
ETHYLENE THIOUREA
ETHYLENIMINE
ETHYL ETHER
ETHYL FORMATE
ETHYLIDENE CHLORIDE
ETHYLIDENE NORBORNENE
ETHYLMORPHOLINE, N-
ETHYL MERCAPTANETHYL METHANE SULPHONATE
ETHYL SILICATE
FENAMIPHOS
FENSULFOTHION
FENTHION
FERBAM
FERROVANADIUM DUST
FIBROUS GLASS DUST
FLUORIDES, AS F
FLUORINE
FLUOROTRICHLOROMETHANE
FONOFOS
FORMALDEHYDE
FORMAMIDE
FORMIC ACID
FORMYLHYDRAZINO)-4(5-NITRO-2-FURYL)THIAZOLE, 2-
FURFURAL
FURFURYL ALCOHOL
GASOLINE
GERMANIUM TETRAHYDRIDE
GLASS, FIBROUS OR DUST
GLUTARALDEHYDE
GLYCERIN MIST
GLYCIDALDEHYDE
GLYCIDOL
GLYCOL MONOETHYL ETHER
GRAIN DUST (OAT, WHEAT, BARLEY)
GRAPHITE (NATURAL)
GRAPHITE (SYNTHETIC)
GUTHION
GYPSUM
HAFNIUM
HALOTHANE
HELIUM
HEMATITE UNDERGROUND MINING
HEPTACHLOR AND HEPTACHLOR EPOXIDE
HEPTANE (N-HEPTANE)
HEPTANONE, 2-
HEPTANONE, 3-
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOHEXANE (LINDANE), Y-
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
HEXACHLORONAPHTHALENE
HEXAFLUOROACETONE
HEXAMETHYLENE DIISOCYANATE
HEXAMETHYL PHOSPHORAMIDE
HEXANE (N-HEXANE)
HEXANE, OTHER ISOMERS
HEXANEDIAMINE, 1,6-
HEXANONE, 2-
HEXONE
HEXYL ACETATE, SEC-
HEXYLENE GLYCOL
HYDRAZINE
HYDRAZINE SULFATE
HYDRAZOBENZENE
HYDROGEN
HYDROGENATED TERPHENYLS
HYDROGEN BROMIDE
HYDROGEN CHLORIDE
HYDROGEN CYANIDE
HYDROGEN FLUORIDE, AS F
HYDROGEN PEROXIDE
HYDROGEN SELENIDE, AS SE
HYDROGEN SULFIDE
HYDROQUINONE
HYDROXY-4-METHYL-2-PENTANONE, 4-
HYDROXYPROPYL ACRYLATE, 2-
INDENE
INDENO(1,2,3-CD)PYRENE
INDIUM & COMPOUNDS, AS IN
IODINE
IODOFORM
IRON DEXTRAN COMPLEX
IRON OXIDE FUME (Fe2O3), AS FE
IRON PENTACARBONYL, AS FE
IRON SALTS, SOLUBLE, AS FE
ISOAMYL ACETATE
ISOAMYL ALCOHOL
ISOBUTYL ACETATE
ISOBUTYL ALCOHOL
ISOOCTYL ALCOHOL
ISOPHORONE
ISOPHORONE DIISOCYANATE
ISOPROPOXYETHANOL
ISOPROPYL ACETATE
ISOPROPYL ALCOHOL
ISOPROPYLAMINE
ISOPROPYLANILINE, N-
ISOPROPYL ETHER
ISOPROPYL GLYCIDYL ETHER (IGE)
ISOPROPYL OIL
KAOLIN
KEPONE
KETENE
LASIOCARPINE
LEAD, INORG. DUST & FUMES, AS PB
LEAD ACETATE
LEAD ARSENATE, AS PbHAsO4
LEAD CHROMATE, AS CR
LEAD PHOSPHATE
LIMESTONE
LINDANE
LITHIUM HYDRIDE
L.P.G. (LIQUIFIED PETROLEUM GAS)
MAGENTA MANUFACTURE
MAGNESITE
MAGNESIUM OXIDE FUME
MALATHION
MALEIC ANHYDRIDE
MALONONITRILEMANGANESE DUST & COMPOUNDS
MANGANESE FUME
MANGANESE CYCLOPENTADIENYL TRI-CARBONYL, AS MN
MANGANESE TETROXIXDE, (AS MN)
MARBLE
MEDROXYPROGESTERONE ACETATE
MEGESTROL ACETATE
MELPHALAN
MERCURY, ALKYL COMPOUNDS, AS HG
MERCURY, ALL FORMS EXCEPT ALKYL VAPOR, AS HG
MERCURY, ARYL & INORGANIC COMPOUNDS, AS HG
MERPHALAN
MESITYL OXIDE
METHACRYLIC ACID
METHANE
METHANETHIOL
METHANOL
METHOMYL
METHOXYCHLOR
METHOXYETHANOL, 2-
METHOXYETHYL ACETATE, 2-
METHOXYPHENOL, 4-
METHYL ACETATE
METHYL ACETYLENE
METHYL ACETYLENE-PROPADIENE MIXTURE (MAPP)
METHYL ACRYLATE
METHYLACRYLONITRILE
METHYLAL
METHYL ALCOHOL
METHYLAMINE
METHYL AMYL ALCOHOL
METHYL N-AMYL KETONE
METHYL ANILINE, N-
METHYLAZOXYMETHANOL
METHYLAZOXYMETHANOL SULFATE
METHYL BROMIDE
METHYL N-BUTYL KETONE
METHYL CELLOSOLVE
METHYL CELLOSOLVE ACETATE
METHYL CHLORIDE
METHYL CHLOROFORM
METHYLCHRYSENE, 5-
METHYL 2-CYANOACRYLATE
METHYLCYCLOHEXANE
METHYLCYCLOHEXANOL
METHYLCYCLOHEXANONE, O-
METHYLCYCLOPENTADIENYL MAN- GANESE TRICARBONYL, AS MN
METHYL DEMETON
METHYLENE BISPHENYL ISOCYANATE
METHYLENE CHLORIDE
METHYLENE BIS(2-CHLOROANILINE) 4,4'-
METHYLENE BIS(4-CYCLO-HEXYLISOCYANATE)
METHYLENE DIANILINE, 4,4-
METHYLENE BIS (2-METHYL-ANILINE), 4,4'-
METHYLENE BIS (N,N-DIMETHYL)
BENZENAMINE, 4,4'-
METHYL ETHYL KETONE
METHYL ETHYL KETONE PEROXIDE
METHYL FORMATE
METHYL HYDRAZINE
METHYL IODIDE
METHYL ISOAMYL KETONE
METHYL ISOBUTYL CARBINOL
METHYL ISOBUTYL KETONE
METHYL ISOCYANATE
METHYL ISOPROPYL KETONE
METHYL MERCAPTAN
METHYL METHACRYLATE
METHYL METHANESULPHONATE
METHYL-1-NITROANTHRAQUINONE, 2-
METHYL-N'-NITRO-N-NITROSO-GUANIDINE, N-
METHYL PARATHION
METHYL PROPYL KETONE
METHYL SILICATE
METHYL STYRENE, ALPHA-
METHYLTHIOURACIL
METRIBUZIN
METRONIDAZOLE
MEVINPHOS
MICA
MICHLER'S KETONE
MINERAL WOOL FIBER
MIREX
MITOMYCIN C
MOLYBDENUM, SOLUBLE COMPOUNDS, AS MO
MOLYBDENUM, INSOLUBLE COMPUNDS, AS MO
MONOCHLOROBENZENE
MONOCHLORODIMETHYL ETHER
MONOCROTALINE
MONOCROTOPHOS
MORPHOLINE
(MORPHOLINOMETHYL)-3-[(5-NITRO-FURFURYLIDENE)AMINO], 2-OXAZO-LIDENONE, 5-
MUSTARD GAS
NAFENOPIN
NALED
NAPHTHA (COAL TAR)
NAPHTHALENE
NAPHTHALENE DIISOCYANATE (NDI)
NAPHTHYLAMINE, ALPHA-
NAPHTHYLAMINE, BETA-
NEON
NICKEL, METAL
NICKEL, INSOLUBLE COMPOUNDS, AS NINICKEL, SOLUBLE COMPOUNDS, AS NI
NICKEL CARBONYL, AS NI
NICKEL SULFIDE ROASTING, FUME & DUST, AS NI
NICOTINE
NIRIDAZOLE
NITRAPYRIN
NITRIC ACID
NITRIC OXIDE
NITRILOTRIACETIC ACID (NTA)
NITROACENAPHTHENE, 5-
NITRO-4-AMINOPHENOL, 2-
NITRO-2-AMINOTOLUENE, 4-
NITROANILINE, P-
NITROBENZENE
NITROBIPHENYL, 4-
NITROCHLOROBENZENE, P-
NITRODIPHENYL, 4-
NITROETHANE
[(NITROFURFURYLIDENE)AMINE]-2-IMIDAZOLIDINONE, 1- [4-(5-NITRO-2-FURYL)-2-THI AZOLYL]ACETAMIDE, N-
NITROGEN
NITROGEN DIOXIDE
NITROGEN MUSTARD
NITROGEN MUSTARD N-OXIDE
NITROGEN TRIFLUORIDE
NITROGLYCERIN (NG)
NITROMETHANE
NITRO-O-ANISIDINE, 5-
NITROPROPANE, 1-
NITROPROPANE, 2-
NITROPYRENES MONO-, DI-, TRI-, TETRA-ISOMERS
NITROSODI-N-BUTYLAMINE, N- (DBN)
NITROSODIETHANOLAMINE, N-(NDELA)
NITROSODIETHYLAMINE, N- (NDEA)
NITROSODIMETHYLAMINE, N-
NITROSODIPHENYLAMINE, P-
NITROSODI-N-PROPYLAMINE, N- (NDPA)
NITROSO-N-ETHYLUREA, N- (ENU)
NITROSOMETHYLETHYLAMINE, N-
NITROSO-N-METHYLUREA, N- (NMU)
NITROSOMETHYLVINYLAMINE, N- (NMVA)
NITROSOMORPHOLINE, N- (NMOR)
NITROSONORNICOTINE, N- (NNN)
NITROSOPIPERIDINE, N- (NPIP)
NITROSOPYRROLIDINE, N- (NPYR)
NITROSOSARCOSINE, N- (NSAR)
NITROTOLUENE, O-
NITROTOLUENE, M-
NITROTOLUENE, P-
NITROCHLOROMETHANE
NITROUS OXIDE
NONANE
NONYLMERCAPTAN, N-
NUISANCE PARTICULATES
OCTACHLORONAPHTHALENE
OCTANE
OIL MIST, MINERAL
OIL ORANGE SS
OSMIUM TETROXIDE, AS OS
OXALIC ACID
OXYDIANILINE, 4,4'-
OXYGEN DIFLUORIDE
OXYMETHOLONE
OZONE
PANAFURAN S
PARAFFIN WAX FUME
PARAQUAT
PARATHION
PARTIC. POLYCYCLIC AROMATIC
HYDROCARBONS (PPAH)
PARTICULATES NOT OTHERWISE
CLASSIFIED (PNOC)
PENTABORANE
PENTACHLORONAPHTHALENE
PENTACHLORONITROBENZENE
PENTACHLOROPHENOL
PENTAERYTHRITOL
PENTANE
PENTANONE, 2-
PERCHLOROETHYLENE
PERCHLOROMETHYL MERCAPTAN
PERCHLORYL FLUORIDE
PERFLUOROISOBUTYLENE
PERLITE
PETROLEUM DISTILLATES
PHENACETIN
PHENACYL CHLORIDE
PHENAZOPYRIDINE
PHENAZOPYRIDINE HYDROCHLORIDE (PAP)
PHENOL
PHENOTHIAZINE
PHENOXYACETIC ACID HERBICIDES
PHENOXYBENZAMINE HYDROCHLORIDE
PHENYL-BETA-NAPHTHYLAMINE, N-
PHENYLENEDIAMINE, M-
PHENYLENEDIAMINE, O-
PHENYLENEDIAMINE, P-
PHENYL ETHER, VAPOR
PHENYL ETHER-BIPHENYL MIXTURE, VAPOR
PHENYLETHYLENE
PHENYL GLYCIDYL ETHER (PGE)
PHENYLHYDRAZINE
PHENYL MERCAPTAN
PHENYLPHOSPHINE
PHENYTOIN (+ SODIUM SALT)
PHORATE
PHOSDRIN
PHOSGENE
PHOSPHINE
PHOSPHORIC ACID
PHOSPHORUS (YELLOW)
PHOSPHORUS OXYCHLORIDE
PHOSPHORUS PENTACHLORIDE
PHOSPHORUS PENTASULFIDE
PHOSPHORUS TRICHLORIDE
PHTHALLIC ANHYDRIDE
PHTHALODINITRILE, M-
PICLORAM
PICRIC ACID
PINDONE
PIPERAZINE DIHYDROCHLORIDE
PIVALYL-1,3-INDANDIONE, 2-
PLASTER OF PARIS
PLATINUM, METAL
PLATINUM, SOLUBLE SALTS, AS PT
POLYBROMINATED BIPHENYLS (PBBs)
POLYCHLORINATED BIPHENYLS (PCBs)
POLYCHLOROBIPHENYLS
POLYTETRAFLUOROETHYLENE DE-COMPOSITION PRODUCTS
PONCEAU 3R
PONCEAU MX
PORTLAND CEMENT
POTASSIUM HYDROXIDE
PRECIPITATED SILICA
PROCARBAZINE
PROCARBAZINE HYDROCHLORIDE
PROGESTERONE (INDIRECT)
PROPANE
PROPANE SULTONE
PROPARGYL ALCOHOL
PROPIOLACTONE, BETA-
PROPIONIC ACID
PROPOXUR (BAYGON)
PROPYL ACETATE, N-
PROPYL ALCOHOL, N-
PROPYLENE
PROPYLENE DICHLORIDE
PROPYLENE GLYCOL DINITRATE
PROPYLENE GLYCOL MONOMETHYL ETHER
PROPYLENE IMINE
PROPYLENE OXIDE
PROPYL NITRATE, N-
PROPYLTHIOURACIL
PROPYNE
PYRETHRUM
PYRIDINE
PYROCATECHOL
QUARTZ
QUINONE
RDX
RESERPINE
RESORCINOL
RHODIUM, METAL
RHODIUM, INSOLUBLE COMPOUNDS, AS RH
RHODIUM, SOLUBLE COMPOUNDS, AS RH
RONNEL
ROSIN CORE SOLDER PYROLYSIS
PRODUCTS, AS FORMALDEHYDE
ROTENONE (COMMERCIAL)
ROUGE
RUBBER SOLVENT (NAPHTHA)
SACCHARIN
SAFROLE
SELENIUM AND COMPOUNDS, AS SE
SELENIUM HEXAFLUORIDE, AS SE
SELENIUM SULFIDE
SESONE
SILANE
SILICA-AMORPHOUS, DIATOMACEOUS
EARTH (UNCALCINED)
SILICA-AMORPHOUS, PRECIPITATED SILICA
SILICA-AMORPHOUS, SILICA, FUME
SILICA-AMORPHOUS, SILICA, FUSED
SILICA-AMORPHOUS, SILICA GEL
SILICA-CRYSTALLINE CRISTOBALITE
SILICA-CRYSTALLINE QUARTZ
SILICA-CRYSTALLINE TRIDYMITE
SILICA-CRYSTALLINE TRIPOLI
SILICA, FUSED
SILICA, FUME
SILICA, GEL
SILICA, PRECIPITATED
SILICON
SILICON CARBIDE
SILICON TETRAHYDRIDE
SILVER, METAL
SILVER, SOLUBLE COMPOUNDS, AS AG
SOAPSTONE
SODIUM AZIDE
SODIUM BISULFITE
SODIUM CYCLAMATE
SODIUM, 2,4-DICHLOROPHEN-
OXYETHYL SULFATE
SODIUM FLUOROACETATE
SODIUM HYDROXIDE
SODIUM METABISULFITE
STARCH
STEARATES
STERIGMATOCYSTIN
STIBINE
STODDARD SOLVENT
STREPTOZOTOCIN (STR)
STRONTIUM CHROMATE, AS CR
STRYCHNINE
STYRENE, MONOMER
SUBTILISINS (PROTEOLYTIC ENZYMES AS 100% PURE CRYSTALLINE ENZYME)
SUCROSE
SULFOTEP
SULFUR DIOXIDE
SULFUR HEXAFLUORIDE
SULFURIC ACID
SULFUR MONOCHLORIDE
SULFUR PENTAFLUORIDE
SULFUR TETRAFLUORIDE
SULFURYL FLUORIDE
SULPROFOS
SYSTOX
T, 2,4,5-
TALC (CONTAINING NO ASBESTOS FIBERS)
TALC (CONTAINING ASBESTOS FIBERS)
TANTALUM, METAL
TANTALUM, OXIDE DUSTS
TEDP
TELLURIUM & COMPOUNDS, AS TE
TELLURIUM HEXAFLUORIDE, AS TE
TEMEPHOS
TEPP (TETRAETHYL DITHIO-PYROPHOSPHATE)
TERPHENYLS
TESTOSTERONE
TETRABROMOETHANE, 1,1,2,2-
TETRACHLORODIBENZO-P-DIOXIN (TCDD), 2,3,7,8,-
TETRACHLORO-1,2-DIFLUOROETHANE1,1,1,2-
TETRACHLORO-2,2-DIFLUOROETHANE1,1,2,2-
TETRACHLOROETHANE, 1,1,1,2-
TETRACHLOROETHANE, 1,1,2,2-
TETRACHLOROETHYLENE
TETRACHLOROMETHANE
TETRACHLORONAPHTHALENE
TETRAETHYL LEAD, AS PB
TETRAHYDROFURAN
TETRAMETHYL LEAD, AS PB
TETRAMETHYL SUCCINONITRILE
TETRANITROMETHANE
TETRASODIUM PYROPHOSPHATE
TETRYL
THALLIUM, SOLUBLE COMPOUNDS, AS TI
THIOACETAMIDE (TAA)
THIOBIS(6-TERT-BUTYL-M-CRESOL), 4,4'-
THIODIANILINE, 4,4'-
THIOGLYCOLIC ACID
THIONYL CHLORIDE
THIOUREA
THIRAM
THORIUM DIOXIDE
TIN, METAL
TIN, OXIDE, & INORGANIC COMPOUNDS, EXCEPT SnH4, AS SN
TIN, ORGANIC COMPOUNDS, AS SN
TIN OXIDE
TITANIUM DIOXIDE
TOLIDINE, O-
TOLUENE
TOLUENE-2,4-DIAMINE
TOLUENE-2,4-DIISOCYANATE (TDI)
TOLUIDINE, O-
TOLUIDINE, M-
TOLUIDINE, P-
TOLUIDINE HYDROCHLORIDE, O-
TOLUOL
TOXAPHENE
TREMOLITE
TREOSULPHAN
TRIBUTYL PHOSPHATE
TRICHLOROACETIC ACID
TRICHLOROBENZENE, 1,2,4-
TRICHLOROETHANE, 1,1,1-
TRICHLOROETHANE, 1,1,2-
TRICHLOROETHYLENE
TRICHLOROFLUOROMETHANE
TRICHLOROMETHANE
TRICHLORONAPHTHALENE
TRICHLORONITROMETHANE
TRICHLOROPHENOL, 2,4,6-
TRICHLOROPHENOXYACETIC ACID, 2,4,5-
TRICHLOROPROPANE, 1,2,3-
TRICHLORO-1,2,2-TRIFLUORO-ETHANE, 1,1,2-
TRICYCLOHEXYLTIN HYDROXIDE
TRIDYMITE
TRIETHANOLAMINE
TRIETHYLAMINE
TRIFLUOROBROMOMETHANE
TRIMELLITIC ANHYDRIDE
TRIMETHYLAMINE
TRIMETHYLANILINE, 2,4,5-TRIMETHYL BENZENE
TRIMETHYL PHOSPHATE
TRIMETHYL PHOSPHITE
TRINITROPHENOL, 2,4,6-
TRINITROPHENYLMETHYL-NITRAMINE, 2,4,6-
TRINITROTOLUENE, 2,4,6- (TNT)
TRIOTHOCRESYL PHOSPHATE
TRIPHENYL AMINE
TRIPHENYL PHOSPHATE
TRIPOLI
TRIS(AZIRIDINYL)-PARA-BENZOQUINONE
TRIS (1-AZIRIDINYL) PHOSPHINE SULFIDE (THIOTEPA)
TRIS(2,3-DIBROMOPROPYL) PHOSPHATE (TRIS)
TRYPAN BLUE (COMMERCIAL GRADE)
TUNGSTEN, INSOLUBLE COMPOUNDS, AS W
TUNGSTEN, SOLUBLE COMPOUNDS, AS W
TURPENTINE
URACIL MUSTARD
URANIUM (NATURAL), SOLUBLE & INSOLUBLE COMPOUNDS, AS U
URETHANE (ETHYL CARBAMATE)
VALERALDEHYDE, N-
VANADIUM, AS V2O5, RESPIRABLE DUST & FUME
VEGETABLE OIL MISTS
VINYL ACETATE
VINYL BENZENE
VINYL BROMIDE
VINYL CHLORIDE
VINYL CYANIDE
VINYL CYCLOHEXENE
VINYL CYCLOHEXENE DIOXIDE
VINYL FLUORIDE
VINYL TOLUENE
VINYLIDENE CHLORIDE
VINYLIDENE FLUORIDE MONOMER
VM & P NAPTHA
WARFARIN
WELDING FUMES (NOC)
WOOD DUST, (CERTAIN HARD WOODS AS BEECH & OAK)
WOOD DUST, SOFT WOOD
WOOD DUST, WESTERN RED CEDAR
XYLENE (O-, M-, P-ISOMERS)
XYLENE-ALPHA,ALPHA'-DIAMINE, M-
XYLIDINE (MIXED ISOMERS)
YTTRIUM METAL & COMPOUNDS, AS Y
ZINC BERYLLIUM SILICATE
ZINC CHLORIDE FUME
ZINC CHROMATES, AS CR
ZINC OXIDE, FUME
ZINC OXIDE, DUST
ZINC STEARATE
ZIRCONIUM COMPOUNDS, AS ZR
TRAINING SESSION OUTLINE AND FORMAT
- TRAINER:
- BUILDING AND LOCATION:
- C/I/O:
- TRAINING TOPIC(S):
ATTACH COPIES OF ALL HANDOUTS PROVIDED TO TRAINEES.
TRAINING OUTLINE
FORMAT USED (VIDEOTAPE, FILM, SLIDES, SPEAKER, ETC.)
Chemical Safety Manual Contents
Health and Safety Manual Contents
Office of Health and Safety, Centers for Disease Control and Prevention,
1600 Clifton Road N.E., Mail Stop F05 Atlanta, Georgia 30333, USA
Last Modified: 1/2/97Send us your Comments.